Some trends in the development of microplasmas for spectrochemical analysis

被引：31

作者：

Broekaert, JAC ^{[1
]}

Siemens, V ^{[1
]}

机构：

[1] Univ Hamburg, Inst Inorgan & Appl Chem, D-20146 Hamburg, Germany

来源：

ANALYTICAL AND BIOANALYTICAL CHEMISTRY | 2004年 / 380卷 / 02期

关键词：

atomic spectrometry; microplasma; plasma-on-the-chip; plasma spectrometry;

D O I：

10.1007/s00216-004-2635-9

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The development of microplasmas for spectrochemical analysis by optical methods is discussed. Recent achievements in miniaturization are highlighted, especially for three types of plasmas, namely high-frequency plasmas, dc-discharges and microwave plasmas. The potentials of each of these groups of plasmas as sources for atomic emission spectrometry are discussed. Literature citations and experiments indicate that the plasmas are also very useful as atom reservoirs for atomic absorption spectrometry. Methods of sampling, including feeding with gas chromatography effluents, the use of electrothermal vaporization, and the evolution of gaseous species (as shown for the case of Hg vapor), are discussed as prominent interfaces to make use of these sources for elemental analysis.

引用

页码：185 / 189

页数：5

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