A general and practical Lewis acids-catalyzed aryl formates synthesis

被引：5

作者：

Jiang, Li-Bing ^{[1
]}

Li, Rui ^{[1
]}

Zhou, Chao ^{[1
]}

Qi, Xinxin ^{[1
]}

Peng, Jin-Bao ^{[1
]}

Wu, Xiao-Feng ^{[1
,2
]}

机构：

[1] Zhejiang Sci Tech Univ, Dept Chem, Xiasha Campus, Hangzhou 310018, Zhejiang, Peoples R China

[2] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

MOLECULAR CATALYSIS | 2017年 / 433卷

关键词：

Aryl formates; Phenol; Formic acid; Lewis acid; CO surrogate; EXTERNAL CARBON-MONOXIDE; CO SOURCE; CARBONYLATION; HALIDES; REAGENT; ACYLATION; PHENOLS; ALKENYL;

D O I：

10.1016/j.mcat.2017.02.003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A general and practical Lewis acids catalyzed synthesis of aryl formates has been established. With catalytic amount of cheap metal as the catalyst, good to excellent yields of aryl formates can be isolated with good functional group tolerance. Formic acid has been applied as the formyl source and triflate salts of zinc, manganese and copper are all suitable catalysts here. (C) 2017 Elsevier B. V. All rights reserved.

引用

页码：8 / 11

页数：4

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