Synthesis, crystal structure, physicochemical characterization, and dielectric properties of a new organic chloride salt, (C3H7N6)Cl•0.5H2O

被引：8

作者：

Mesbeh, Radhia ^{[1
]}

Hamdi, Besma ^{[1
]}

Zouari, Ridha ^{[1
]}

机构：

[1] Fac Sci Sfax, Lab Sci Mat & Environm, BP 1171, Sfax 3000, Tunisia

来源：

IONICS | 2019年 / 25卷 / 12期

关键词：

Crystal structure; Dielectric measurements; Vibrational study; Optical properties; Differential scanning calorimetric (DSC); Hirshfeld surface; INFRA-RED SPECTRUM; OPTICAL-PROPERTIES; ELECTRICAL-PROPERTIES; VIBRATIONAL-SPECTRA; MAGNETIC-PROPERTIES; HYBRID COMPOUND; CONDUCTIVITY; SPECTROSCOPY; TRANSITIONS; TRIAZINE;

D O I：

10.1007/s11581-019-03092-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The crystallization of (C3H7N6)Cl center dot 0.5H(2)O is made by slow evaporation at room temperature. It was found to crystallize in the monoclinic system, C2/m space group, with the following lattice parameters: a = 12.4124 (5) angstrom, b = 17.6339 (7) angstrom, c = 7.1193 (3) angstrom, beta = 115.057 (2)degrees, Z = 4, and V = 1411.61 (10) angstrom(3). The cohesion in (C3H7N6)Cl center dot 0.5H(2)O is provided by three types of hydrogen bonds, O-H horizontal ellipsis Cl, N-H horizontal ellipsis O, N-H horizontal ellipsis Cl, and N-H horizontal ellipsis N. Furthermore, the room temperature IR and Raman spectra of the title compound were recorded and analyzed on the basis of literature data. The optical study was also investigated by UV-Vis absorption. The differential scanning calorimetric (DSC) and dielectric study of this compound has been measured. The percentages of hydrogen bonding interactions are analyzed by fingerprint plots of Hirshfeld surface.

引用

页码：6147 / 6160

页数：14

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