High-yield catalytic synthesis of thin multiwalled carbon nanotubes

被引:76
作者
Jeong, HJ
Kim, KK
Jeong, SY
Park, MH
Yang, CW
Lee, YH [1 ]
机构
[1] Sungkyunkwan Univ, Dept Phys, Inst Basic Sci,Ctr Nanotubes & Nanostruct Compos, Natl Res Lab Carbon Nanotubes, Suwon 440746, South Korea
[2] Sungkyunkwan Univ, Dept Adv Mat Engn, Ctr Nanotubes & Nanostruct Compos, Suwon 440746, South Korea
关键词
D O I
10.1021/jp046152o
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have synthesized thin multiwalled carbon nanotubes (t-MWNTs) using a catalytic chemical vapor deposition (CCVD) method with FeMoMgO catalyst. The number of tube walls were 2similar to6 with the corresponding diameters of 3similar to6 nm. We obtained high production yield of over 3000 wt % compared to the weight of the supplied catalyst. These t-MWNTs revealed the intermediate structural characteristics between single- and multiwalled carbon nanotubes (SWNTs and MWNTs). Critical issues for high yield synthesis of t-MWNTs were further discussed in terms of reduction procedure, growth time, and gas species.
引用
收藏
页码:17695 / 17698
页数:4
相关论文
共 19 条
[1]   Transformation of singlewalled carbon nanotubes to multiwalled carbon nanotubes and onion-like structures by nitric acid treatment [J].
An, KH ;
Jeon, KK ;
Moon, JM ;
Eum, SJ ;
Yang, CW ;
Park, GS ;
Park, CY ;
Lee, YH .
SYNTHETIC METALS, 2004, 140 (01) :1-8
[2]   Raman scattering study of double-wall carbon nanotubes derived from the chains of fullerenes in single-wall carbon nanotubes [J].
Bandow, S ;
Takizawa, M ;
Hirahara, K ;
Yudasaka, M ;
Iijima, S .
CHEMICAL PHYSICS LETTERS, 2001, 337 (1-3) :48-54
[3]   COBALT-CATALYZED GROWTH OF CARBON NANOTUBES WITH SINGLE-ATOMIC-LAYERWALLS [J].
BETHUNE, DS ;
KIANG, CH ;
DEVRIES, MS ;
GORMAN, G ;
SAVOY, R ;
VAZQUEZ, J ;
BEYERS, R .
NATURE, 1993, 363 (6430) :605-607
[4]   Fully sealed, high-brightness carbon-nanotube field-emission display [J].
Choi, WB ;
Chung, DS ;
Kang, JH ;
Kim, HY ;
Jin, YW ;
Han, IT ;
Lee, YH ;
Jung, JE ;
Lee, NS ;
Park, GS ;
Kim, JM .
APPLIED PHYSICS LETTERS, 1999, 75 (20) :3129-3131
[5]   Synthesis of single-walled carbon nanotube-Co-MgO composite powders and extraction of the nanotubes [J].
Flahaut, E ;
Peigney, A ;
Laurent, C ;
Rousset, A .
JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (02) :249-252
[6]   Double-walled carbon nanotubes fabricated by a hydrogen arc discharge method [J].
Hutchison, JL ;
Kiselev, NA ;
Krinichnaya, EP ;
Krestinin, AV ;
Loutfy, RO ;
Morawsky, AP ;
Muradyan, VE ;
Obraztsova, ED ;
Sloan, J ;
Terekhov, SV ;
Zakharov, DN .
CARBON, 2001, 39 (05) :761-770
[7]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[8]   Narrow diameter distribution of singlewalled carbon nanotubes grown on Ni-MgO by thermal chemical vapor deposition [J].
Jeong, HJ ;
An, KH ;
Lim, SC ;
Park, MS ;
Chang, JS ;
Park, SE ;
Eum, SJ ;
Yang, CW ;
Park, CY ;
Lee, YH .
CHEMICAL PHYSICS LETTERS, 2003, 380 (3-4) :263-268
[9]   Chemical vapor deposition of methane for single-walled carbon nanotubes [J].
Kong, J ;
Cassell, AM ;
Dai, HJ .
CHEMICAL PHYSICS LETTERS, 1998, 292 (4-6) :567-574
[10]  
LEE JY, 2004, UNPUB PHYS REV B