Synthesis and properties of novel N,C,N terdentate skeleton based on 1,3-di(pyridin-2-yl)benzene moiety-new tricks for old dogs

被引:12
作者
Tan, Shuai [2 ]
Wu, Xiugang [1 ]
Zheng, Yanqiong [3 ]
Wang, Yafei [1 ,2 ]
机构
[1] Changzhou Univ, Jiangsu Engn Lab Light Elect Heat Energy Converti, Jiangsu Key Lab Environm Friendly Polymer Mat,Sch, Jiangsu Collaborat Innovat Ctr Photovolta Sci & E, Changzhou 213164, Peoples R China
[2] Xiangtan Univ, Coll Chem, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Xiangtan 411105, Peoples R China
[3] Shanghai Univ, Key Lab Adv Display & Syst Applicat, Minist Educ, Shanghai 200072, Peoples R China
基金
中国国家自然科学基金;
关键词
1,3-Di(pyridin-2-yl)benzene skeleton; Platinum complex; Synthesis; Intramolecular cyclization; PLATINUM(II) COMPLEXES; IRIDIUM(III) COMPLEXES; LIGANDS; CHEMISTRY;
D O I
10.1016/j.cclet.2019.08.003
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Utilization of intermolecular Friedel-Crafts and intramolecular condensation reaction, novel 1,3-di(pyridine-2-yl)benzene(N,C,N terdentate) skeleton with electro-withdrawing group in 6' position of pyridyl and a cyclization between 6' position of pyridyl and 6 position of benzyl ring were firstly designed and synthesized. The structures of these novel N,C,N terdentate were confirmed by NMR, MS and X-ray single crystalanalyses. The photophysical properties of these compounds were briefly explored. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:1951 / 1954
页数:4
相关论文
共 31 条
[1]   Single-flask preparation of polyazatriaryl ligands by sequential borylation/Suzuki-Miyaura coupling [J].
Avitia, Bertoldo ;
MacIntosh, Eric ;
Muhia, Samuel ;
Kelson, Eric .
TETRAHEDRON LETTERS, 2011, 52 (14) :1631-1634
[2]   On the Viability of Cyclometalated Ru(II) Complexes for Light-Harvesting Applications [J].
Bomben, Paolo G. ;
Robson, Kiyoshi C. D. ;
Sedach, Pavel A. ;
Berlinguette, Curtis P. .
INORGANIC CHEMISTRY, 2009, 48 (20) :9631-9643
[3]   Dinuclear Iridium(III) Complexes Containing Bibenzimidazole and Their Application to Water Photoreduction [J].
Cai, Jian-Guang ;
Yu, Zhen-Tao ;
Yuan, Yong-Jun ;
Li, Feng ;
Zou, Zhi-Gang .
ACS CATALYSIS, 2014, 4 (06) :1953-1963
[4]   High-yield synthesis of a C∧N∧C tridentate platinum complex [J].
Cave, GWV ;
Alcock, NW ;
Rourke, JP .
ORGANOMETALLICS, 1999, 18 (09) :1801-1803
[5]   Synthesis and electronic properties of double pincer-type cyclometalated iridium complexes [J].
Choi, Daehyuk ;
Kim, Taehyung ;
Reddy, Samala Malla ;
Kang, Jahyo .
INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (01) :41-44
[6]   Two-step Changes in Luminescence Color of Pt(II) Complex Bearing an Amide Moiety by Mechano- and Vapochromism [J].
Choi, Seong Jib ;
Kuwabara, Junpei ;
Nishimura, Yoshinobu ;
Arai, Tatsuo ;
Kanbara, Takaki .
CHEMISTRY LETTERS, 2012, 41 (01) :65-67
[7]   N∧C∧N-coordinated platinum(II) complexes as phosphorescent emitters in high-performance organic light-emitting devices [J].
Cocchi, Massimo ;
Virgili, Dalia ;
Fattori, Valeria ;
Rochester, David L. ;
Williams, J. A. Gareth .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (02) :285-289
[8]   Neutral NCN terdentate luminescent Pt(II) complexes: their synthesis, photophysical properties, and bio-imaging applications [J].
Colombo, Alessia ;
Fiorini, Federica ;
Septiadi, Dedy ;
Dragonetti, Claudia ;
Nisic, Filippo ;
Valore, Adriana ;
Roberto, Dominique ;
Mauro, Matteo ;
De Cola, Luisa .
DALTON TRANSACTIONS, 2015, 44 (18) :8478-8487
[9]   ISOQUINOLINES AS RECEPTORS FOR RESORCINOL [J].
DYKER, G ;
GABLER, M ;
NOUROOZIAN, M ;
SCHULZ, P .
TETRAHEDRON LETTERS, 1994, 35 (52) :9697-9700
[10]   Advances on supramolecular assembly of cyclometalated platinum(II) complexes [J].
Fu, Teng-Fei ;
Ao, Lei ;
Gao, Zong-Chun ;
Zhang, Xiao-Long ;
Wang, Feng .
CHINESE CHEMICAL LETTERS, 2016, 27 (08) :1147-1154