Effect of NaCl and KCl on volumetric and acoustic behavior of aqueous Creatinine Hydrochloride solutions at T = (288.15-318.15) K

被引：6

作者：

Tangde, Vijay M. ^{[1
]}

Khaty, Niraj T. ^{[2
]}

Bankar, Sneha T. ^{[1
]}

Malladi, Latha ^{[1
]}

Sheikh, Nikhat G. ^{[1
]}

Dhondge, Sudhakar S. ^{[3
]}

Dhondge, Alka S. ^{[4
]}

机构：

[1] Rashtrasant Tukadoji Maharaj Nagpur Univ, Dept Chem, Nagpur 440033, Maharashtra, India

[2] Rashtrasant Tukadoji Maharaj Nagpur Univ, Laxminarayan Inst Technol, Dept Chem, Nagpur 440033, Maharashtra, India

[3] Seth Kesarimal Porwal Coll, Dept Chem, Nagpur 441001, Maharashtra, India

[4] Lady Amrutabai Daga Coll Arts Commerce & Sci, Dept Biochem, Nagpur 440010, Maharashtra, India

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2021年 / 335卷

关键词：

Apparent molar volume; Isentropic compressibility; Apparent molar isentropic compressibility; Hydration number; Creatinine Hydrochloride and aqueous solution; APPARENT MOLAR VOLUME; SODIUM-CHLORIDE; THERMODYNAMIC PROPERTIES; ORGANIC-COMPOUNDS; WATER; COMPRESSIBILITY; ELECTROLYTE; MYOINOSITOL; SOLVATION; MIXTURES;

D O I：

10.1016/j.molliq.2021.116194

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Systematic measurements of density and speed of sound of Creatinine Hydrochloride in aqueous and in aqueous solutions of 0.06 mol.kg(-1) NaCl/KCl and 0.1 mol.kg(-1) NaCl/KCl were carried out at T = (288.15-318.15) K within the concentration range of (0.03 to 0.1) mol.kg(-1). All the measurements were performed for density and speed of sound simultaneously on Anton Paar DSA 5000 M. The density (rho) and speed of sound (u) were employed to calculate the various derived parameters such as apparent molar volume of solute (V-phi), limiting apparent molar volume of solute (V-phi(0)) limiting apparent molar expansivity (E-phi(0)), thermal expansion coefficient (alpha*), isentropic compressibility (k(s)), apparent molar isentropic compressibility (K-s,K-phi), limiting apparent molar compressibility (K-s phi(0)). The trends of variation of experimental and computed parameters have been discussed in terms of hydrophilic-ionic group interactions and hydrophilic-hydrophilic interactions operative in the systems. (C) 2021 Elsevier B.V. All rights reserved.

引用

页数：16

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