Stereochemical, biochemical and ligation behaviour of divalent platinum complexes of sulfur and nitrogen donor agents

被引：17

作者：

Fahmi, N ^{[1
]}

Biyala, MK ^{[1
]}

Singh, RV ^{[1
]}

机构：

[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India

来源：

TRANSITION METAL CHEMISTRY | 2004年 / 29卷 / 06期

关键词：

D O I：

10.1007/s11243-004-6580-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Divalent Pt complexes of o-FC6H4C(H)NNC(SH)SCH2Ph((LH)-H-1) and o-FC6H4C(Me)NNC(SH)SCH2Ph(L2H) have been synthesized and characterized thoroughly by analytical data, conductance measurements, molecular weight determinations, magnetic measurements, i.r., electronic, H-1-n.m.r. and F-19-n.m.r. spectral studies. The spectral data are consistent with a square planar geometry around Pt-II in which the ligand acts as a neutral bidentate and monobasic bidentate ligand coordinating through nitrogen and sulfur atoms. Ligands and their metal complexes were tested against certain microorganisms to assess their antimicrobial properties and the results are indeed positive.

引用

页码：681 / 683

页数：3

共 16 条

[1] 5-COORDINATE COPPER(II) COMPLEXES - SYNTHESIS AND PROPERTIES OF [CU(TREN)L]2+ CATIONS [J].