Improving the spectral qualities of major elements in soil by controlling the ambient pressure in time-resolved laser-induced breakdown spectroscopy

被引:5
作者
Yi, Rongxing [1 ]
Yang, Xinyan [2 ]
Lin, Fangrui [1 ]
Ren, Sheng [1 ]
机构
[1] Shenzhen Univ, Coll Optoelect Engn, Key Lab Optoelect Devices & Syst Guangdong Prov, Shenzhen 518060, Guangdong, Peoples R China
[2] Anhui Normal Univ, Dept Phys, Anhui Prov Key Lab Optoelect Mat Sci & Technol, Wuhu 241000, Anhui, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
ACCURACY IMPROVEMENT; LIBS; SPECTROMETRY;
D O I
10.1364/AO.58.008824
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Laser-induced breakdown spectroscopy (LIES) is a powerful tool in the soil monitoring field, but the poor spectral quality limits its application. To improve the spectral quality of major elements in soil samples, a method based on controlling the ambient pressure and time sequence was introduced. Spectral qualities that include signal-to-background ratio (SBR), spectral stability, and spectral profile were all studied in different ambient pressures and delay times. The results show that the SBRs of Na and K elements increased from 20 to about 300, when the air pressure and delay time were controlled. Meanwhile, the relative standard deviations were improved from more than 30% to less than 5% due to the release of the self-absorption effect. This work proved that the spectral qualities of LIBS can be improved a lot by controlling the ambient pressure in the field of detecting major elements in soil. (C) 2019 Optical Society of America
引用
收藏
页码:8824 / 8828
页数:5
相关论文
共 21 条
[1]   Laser-induced breakdown spectroscopy for simultaneous determination of Sm, Eu and Gd in aqueous solution [J].
Alamelu, D. ;
Sarkar, A. ;
Aggarwal, S. K. .
TALANTA, 2008, 77 (01) :256-261
[2]  
[Anonymous], 2012, LASER INDUCED BREAK, DOI DOI 10.1007/978-3-642-20668-97
[3]   Classification of Brazilian soils by using LIBS and variable selection in the wavelet domain [J].
Coelho Pontes, Marcio Jose ;
Cortez, Juliana ;
Harrop Galvao, Roberto Kawakami ;
Pasquini, Celio ;
Ugulino Araujo, Mario Cesar ;
Coelho, Ricardo Marques ;
Chiba, Marcio Koiti ;
de Abreu, Monica Ferreira ;
Madari, Beata Emoeke .
ANALYTICA CHIMICA ACTA, 2009, 642 (1-2) :12-18
[4]   Laser induced breakdown spectroscopy library for the Martian environment [J].
Cousin, A. ;
Forni, A. ;
Maurice, S. ;
Gasnault, O. ;
Fabre, C. ;
Sautter, V. ;
Wiens, R. C. ;
Mazoyer, J. .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2011, 66 (11-12) :805-814
[5]   A method for improving the accuracy of calibration-free laser-induced breakdown spectroscopy (CF-LIBS) using determined plasma temperature by genetic algorithm (GA) [J].
Dong, Juan ;
Liang, Long ;
Wei, Jiao ;
Tang, Hongsheng ;
Zhang, Tianlong ;
Yang, Xiaofeng ;
Wang, Kang ;
Li, Hua .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2015, 30 (06) :1336-1344
[6]   Extending the applicability of laser-induced breakdown spectroscopy for total soil carbon measurement [J].
Ebinger, MH ;
Norfleet, ML ;
Breshears, DD ;
Cremers, DA ;
Ferris, MJ ;
Unkefer, PJ ;
Lamb, MS ;
Goddard, KL ;
Meyer, CW .
SOIL SCIENCE SOCIETY OF AMERICA JOURNAL, 2003, 67 (05) :1616-1619
[7]  
Eschlbock-Fuchs S., 2015, J ANAL ATOM SPECTROM, V109, P31
[8]   Determination of boron with molecular emission using laser-induced breakdown spectroscopy combined with laser-induced radical fluorescence [J].
Guo, L. B. ;
Zhu, Z. H. ;
Li, J. M. ;
Tang, Y. ;
Tang, S. S. ;
Hao, Z. Q. ;
Li, X. Y. ;
Lu, Y. F. ;
Zeng, X. Y. .
OPTICS EXPRESS, 2018, 26 (03) :2634-2642
[9]  
Guo L.-B., 2016, REC TECHN PROGR AS 1
[10]   Investigation on self-absorption at reduced air pressure in quantitative analysis using laser-induced breakdown spectroscopy [J].
Hao, Z. Q. ;
Liu, L. ;
Shen, M. ;
Yang, X. Y. ;
Li, K. H. ;
Guo, L. B. ;
Li, X. Y. ;
Lu, Y. F. ;
Zeng, X. Y. .
OPTICS EXPRESS, 2016, 24 (23) :26521-26528