Synthesis of phosphorus-doped soft carbon as anode materials for lithium and sodium ion batteries

被引:13
作者
Wang, H. B. [2 ]
Yu, Q. [2 ]
Qu, J. [1 ]
机构
[1] Changzhou Univ, Sch Mat Sci & Engn, Changzhou 213164, Peoples R China
[2] China Aviat Lithium Battery Co Ltd, Luoyang 471003, Peoples R China
基金
中国国家自然科学基金;
关键词
phosphorus-doped; soft carbon; lithium ion battery; sodium ion battery; INSERTION; GRAPHITE;
D O I
10.1134/S0036024417060292
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Phosphorus-doped soft carbon was synthesized by a facile phosphoric acid-assisted route. It is found that the phosphorus-doped soft carbon used as lithium ion battery anode exhibits a high reversible capacity of 333.6 mA h g(-1) with the first cycle coulombic efficiency of 87.0% at the current density of 30 mA g(-1). When used as sodium ion battery anode, it also shows great storage performance, with a reversible capacity of 121.3 mA h g(-1) with an initial coulombic efficiency of 65.0% at the current density of 10 mA g(-1). Besides, good rate capability and stable cycling performance are also observed for both lithium and sodium ion batteries, indicating potential of their application in large-scale storage devices.
引用
收藏
页码:1152 / 1155
页数:4
相关论文
共 16 条
[1]   Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications [J].
Cao, Yuliang ;
Xiao, Lifen ;
Sushko, Maria L. ;
Wang, Wei ;
Schwenzer, Birgit ;
Xiao, Jie ;
Nie, Zimin ;
Saraf, Laxmikant V. ;
Yang, Zhengguo ;
Liu, Jun .
NANO LETTERS, 2012, 12 (07) :3783-3787
[2]   Recent development of carbon materials for Li ion batteries [J].
Endo, M ;
Kim, C ;
Nishimura, K ;
Fujino, T ;
Miyashita, K .
CARBON, 2000, 38 (02) :183-197
[3]   Hierarchically Porous Li4Ti5O12 Anode Materials for Li- and Na-Ion Batteries: Effects of Nanoarchitectural Design and Temperature Dependence of the Rate Capability [J].
Hasegawa, George ;
Kanamori, Kazuyoshi ;
Kiyomura, Tsutomu ;
Kurata, Hiroki ;
Nakanishi, Kazuki ;
Abe, Takeshi .
ADVANCED ENERGY MATERIALS, 2015, 5 (01)
[4]   Thermal and electrochemical studies of carbons for Li-ion batteries 1. Thermal analysis of petroleum and pitch cokes [J].
Jiang, W ;
Tran, T ;
Song, X ;
Kinoshita, K .
JOURNAL OF POWER SOURCES, 2000, 85 (02) :261-268
[5]   Increasing reversible capacity of soft carbon anode by phosphoric acid treatment [J].
Jo, Yong-Nam ;
Park, Min-Sik ;
Lee, Eun-Young ;
Kim, Jae-Geun ;
Houg, Ki-Joo ;
Lee, Sang-Ick ;
Jeong, Hu Young ;
Ryu, Gyeong Hee ;
Lee, Zonghoon ;
Kim, Young-Jun .
ELECTROCHIMICA ACTA, 2014, 146 :630-637
[6]   Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries [J].
Kim, Sung-Wook ;
Seo, Dong-Hwa ;
Ma, Xiaohua ;
Ceder, Gerbrand ;
Kang, Kisuk .
ADVANCED ENERGY MATERIALS, 2012, 2 (07) :710-721
[7]   Spherical hard carbon prepared from potato starch using as anode material for Li-ion batteries [J].
Li, Wenbin ;
Chen, Mingming ;
Wang, Chengyang .
MATERIALS LETTERS, 2011, 65 (23-24) :3368-3370
[8]   Room-temperature stationary sodium-ion batteries for large-scale electric energy storage [J].
Pan, Huilin ;
Hu, Yong-Sheng ;
Chen, Liquan .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (08) :2338-2360
[9]   Lithium batteries: Status, prospects and future [J].
Scrosati, Bruno ;
Garche, Juergen .
JOURNAL OF POWER SOURCES, 2010, 195 (09) :2419-2430
[10]   Na2Ti3O7: Lowest Voltage Ever Reported Oxide Insertion Electrode for Sodium Ion Batteries [J].
Senguttuvan, Premkumar ;
Rousse, Gwenaelle ;
Seznec, Vincent ;
Tarascon, Jean-Marie ;
Rosa Palacin, M. .
CHEMISTRY OF MATERIALS, 2011, 23 (18) :4109-4111