Thiosulfate leaching of gold from waste mobile phones

被引:158
作者
Vinh Hung Ha [2 ]
Lee, Jae-chun [1 ]
Jeong, Jinki [1 ]
Huynh Trung Hai [2 ]
Jha, Manis K. [3 ]
机构
[1] Korea Inst Geosci & Mineral Resources, Mineral Resources Res Div, Taejon 305350, South Korea
[2] Hanoi Univ Technol, Inst Environm Sci & Technol, Hanoi, Vietnam
[3] CSIR, Natl Met Lab, Met Extract & Forming Div, Jamshedpur, Bihar, India
基金
新加坡国家研究基金会;
关键词
Gold; Thiosulfate leaching; Mobile phone; PCBs; Recycling; AQUEOUS AMMONIA; OXIDATION; COPPER; OXYGEN; KINETICS;
D O I
10.1016/j.jhazmat.2010.01.099
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The present communication deals with the leaching of gold from the printed circuit boards (PCBs) of waste mobile phones using an effective and less hazardous system, i.e., a copper-ammonia-thiosulfate solution, as an alternative to the conventional and toxic cyanide leaching of gold. The influence of thiosulfate, ammonia and copper sulfate concentrations on the leaching of gold from PCBs of waste mobile phones was investigated. Gold extraction was found to be enhanced with solutions containing 15-20 mM cupric, 0.1-0.14M thiosulfate, and 0.2-0.3 M ammonia. Similar trends were obtained for the leaching of gold from two different types of scraps and PCBs of waste mobile phones. From the scrap samples, 98% of the gold was leached out using a solution containing 20 mM copper, 0.12 M thiosulfate and 0.2 M ammonia. Similarly, the leaching of gold from the PCBs samples was also found to be good, but it was lower than that of scrap samples in similar experimental conditions. In this case, only 90% of the gold was leached, even with a contact time of 10 h. The obtained data will be useful for the development of processes for the recycling of gold from waste mobile phones. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1115 / 1119
页数:5
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