Easy preparation of cobalt corrole and hexaphyrin and isolation of new oligopyrroles in the solvent-free condensation of pyrrole with pentafluorobenzaldehyde

被引：44

作者：

Simkhovich, L

Goldberg, I ^{[1
]}

Gross, Z

机构：

[1] Tel Aviv Univ, Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

[2] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel

[3] Technion Israel Inst Technol, Inst Catalysis Sci & Technol, IL-32000 Haifa, Israel

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 08期

关键词：

D O I：

10.1021/ol0341142

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Following the discovery that meso-substituted corroles are formed in solvent-free condensation of pyrrole with aldehydes, we demonstrate that a small variation in the methodology is suitable for facile synthesis of cobalt(III) corrole and hexaphyrin. These compounds, as well as three noncyclic products, were fully characterized by spectroscopy and X-ray crystallography.

引用

页码：1241 / 1244

页数：4

共 46 条

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