Hydroperoxides and aryl diazonium salts as reagents for the functionalization of non-activated olefins

被引：17

作者：

Blank, Olga ^{[1
]}

Raschke, Nicole ^{[1
]}

Heinrich, Markus R. ^{[1
,2
]}

机构：

[1] Tech Univ Munich, D-85747 Garching, Germany

[2] Univ Erlangen Nurnberg, D-91052 Erlangen, Germany

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 13期

关键词：

Radical reactions; Hydroperoxides; Olefin functionalization; Arenediazonium salts; ALPHA-ALKOXY HYDROPEROXIDES; FREE-RADICAL REACTIONS; REDUCTIVE CARBODIAZENYLATION; FRAGMENTATION REACTIONS; NITROGEN BONDS; POLAR; CARBOAZIDATION; AZIDATION; CARBON; CONVENIENT;

D O I：

10.1016/j.tetlet.2010.01.098

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydroperoxides, olefins, and arenediazonium salts selectively combine to give azo compounds via an iron(II)-mediated three-component reaction. Starting with a fragmentation liberating acetic acid, the hydro-peroxides act as radical source and the diazonium ions as nitrogen-centered radical scavengers. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：1758 / 1760

页数：3

共 5 条

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[5] Comparative Investigation of the Hydrogen Production of Zinc/carbons Prepared from Non-activated Carbon and Surface-modified Activated Carbon by Treatment with Zinc Salts
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