Synthesis, Structure, and Frequency-Doubling Effect of Calcium Cyanurate

被引：112

作者：

Kalmutzki, Markus ^{[1
]}

Stroebele, Markus ^{[1
]}

Wackenhut, Frank ^{[2
]}

Meixner, Alfred J. ^{[2
]}

Meyer, H. -Juergen ^{[1
]}

机构：

[1] Univ Tubingen, Inst Anorgan Chem, Abt Festkorperchem & Theoret Anorgan Chem, D-72076 Tubingen, Germany

[2] Univ Tubingen, Inst Phys & Theoret Chem, D-72076 Tubingen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 51期

关键词：

cyanurates; solid-state metathesis reactions; frequency doubling; crystal structures; nonlinear optical materials; NONLINEAR-OPTICAL PROPERTIES; CRYSTAL-STRUCTURE;

D O I：

10.1002/anie.201407708

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Calcium cyanurate is synthesized by reacting calcium chloride with potassium cyanate following a solid-state reaction. The formation of the new compound Ca-3(O3C3N3)(2) (CCY), which occurs by the cyclotrimerization of cyanate ions, was examined thermoanalytically and the crystal structure was determined by single-crystal structure analysis. The structure of CCY is closely related to the structure of the well-known oxoborate beta-BaB2O4 (BBO). Second harmonic generation (SHG) measurements on crystal powders show a higher SHG efficiency for CCY than for BBO by about one order of magnitude.

引用

页码：14260 / 14263

页数：4

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