The coal size distribution is one of key factors affecting the briquette manufacture and product quality. Up to now, the quantitative research on coal size composition has not been reported, The article studies quantitatively the coal size composition by the technique of binder and secondary-low cold pressure briquetting and the means of classfying coal materials firstly and combining them and methods of orthogonal design of experiment; The research provides theoretic bases for crushing technology of raw coal and selecting and designing crusher in the process of briquette production.