Occurrence of stilbene glucosides in Upuna borneensis

被引:23
作者
Ito, T
Ali, Z
Iliya, I
Furusawa, M
Tanaka, T
Nakaya, K
Takahashi, Y
Sawa, R
Murata, A
Darnaedi, D
Iinuma, M
机构
[1] Gifu Prefectural Inst Hlth & Environm Sci, Kakamigahara 5040838, Japan
[2] Gifu Pharmaceut Univ, Dept Pharmacognosy, Gifu 5028585, Japan
[3] Microbial Chem Res Ctr, Shinagawa Ku, Tokyo 1410021, Japan
[4] Univ Tokyo, Grad Sch Sci, Bot Gardens, Bunkyo Ku, Tokyo 1120001, Japan
[5] Indonesian Inst Sci, Bogor 16122, Indonesia
关键词
D O I
10.1002/hlca.200490293
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Four new stilbene glucosides, upunosides A (1), B (5), C (6), and D (7), were isolated from the stem of Upuna borneensis (Dipterocarpaceae) together with the three known glucosides 3, 4, and 8. Upunoside A (1) is the first natural instance of a glucoside of a resveratrol pentamer, and its aglycone has a dibenzo-fused bicyclo[5.3.0]octadiene and two dihydrobenzofuran moieties. The relative structure of the aglycone was determined by spectral analysis including 1D and 2D NMR experiments.
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页码:23 / 34
页数:12
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