Towards poly(ester) nanoparticles: recent advances in the synthesis of functional poly(ester)s by ring-opening polymerization

被引：152
作者：
Pounder, Ryan J. [1 ]
Dove, Andrew P. [1 ]
机构：
[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
来源：
POLYMER CHEMISTRY | 2010年 / 1卷 / 03期
关键词：
POLY(BETA-MALIC ACID) DERIVATIVES; BETA-MALIC-ACID; ALIPHATIC POLYESTERS; CLICK CHEMISTRY; EPSILON-CAPROLACTONE; HYDROLYTIC DEGRADATION; BIODEGRADABLE POLYMERS; TRIBLOCK COPOLYMERS; POLY(ALPHA-HYDROXY ACID)S; THERMOPLASTIC ELASTOMERS;
D O I：
10.1039/b9py00327d
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The recent trends in the synthesis of functional poly(ester)s by ring-opening polymerization (ROP) are reviewed. While the use of ROP processes for the synthesis of poly(lactide), poly(lactide-co-glycolide) and several poly(lactone)s has been well studied, the paucity of functional groups available for further reaction limits their application. Recent efforts to expand this available functionality are reviewed focusing on the application of renewable resources in the synthesis of new monomers and the utilization of click chemistry to provide common intermediate polymers in the manipulation of poly(ester) functionality. In turn these advances are leading to a new generation of precisely controlled nanoparticles comprised entirely of poly(ester)s.
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页码：260 / 271
页数：12
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