Esterification of palmitic acid with epichlorohydrin on anion exchange resin catalyst

被引：7
|
作者：
Muresan, Emil Ioan
Oprea, Spiridon
Malutan, Theodor
Vata, Mihai
机构：
[1] Gh Asachi Tech Univ Iassy, Fac Chem Engn, Dept Organ & Biochem Engn, Iasi 700050, Romania
[2] Gh Asachi Tech Univ Iassy, Fac Chem Engn, Dept Nat & Synthet Polymers, Iasi 700050, Romania
来源：
CENTRAL EUROPEAN JOURNAL OF CHEMISTRY | 2007年 / 5卷 / 03期
关键词：
palmitic acid; epichlorohydrin; esterification; kinetics; ion exchange resins;
D O I：
10.2478/s11532-007-0033-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The esterification reaction of palmitic acid with epichlorohydrin catalyzed by an anionic macroporous resin was studied. Purolite A-500 resin proved to be a very effective catalyst in the synthesis of 3-chloro-2-hydroxypropyl palmitate. The effects of certain parameters such as speed of agitation, catalyst particle size, catalyst loading, temperature, initial molar ratio between reactants on the rate of reaction were studied. It was found that the overall rate is intrinsically kinetically controlled. The structure of synthesized ester was confirmed by FTIR and H-1 NMR analyses. (c) Versita Warsaw and Springer-Verlag Berlin Heidelberg. All rights reserved.
引用
收藏
页码：715 / 726
页数：12
相关论文
共 50 条
  • [41] Ion-exchange Resin Catalyzed Esterification of Lactic Acid with Isopropanol: a Kinetic Study
    Toor, Amrit Pal
    Sharma, Mamta
    Thakur, Sakshi
    Wanchoo, R. K.
    BULLETIN OF CHEMICAL REACTION ENGINEERING AND CATALYSIS, 2011, 6 (01) : 39 - 45
  • [42] Zinc oxide as a solid acid catalyst for esterification reaction
    Nagvenkar, Anjani
    Naik, Sajo
    Fernandes, Julio
    CATALYSIS COMMUNICATIONS, 2015, 65 : 20 - 23
  • [43] Deacidification and ethyl biodiesel production from acid soybean oil using a strong anion exchange resin
    Deboni, Taiana Maria
    Medeiros Hirata, Gisele Atsuko
    Shimamoto, Gustavo Giraldi
    Tubino, Matthieu
    de Almeida Meirelles, Antonio Jose
    CHEMICAL ENGINEERING JOURNAL, 2018, 333 : 686 - 696
  • [44] Kinetic investigation of the immobilization of chromotropic acid derivatives onto anion exchange resin
    Savic, Jasmina
    Vasic, Vesna
    Adnadevic, Borivoj
    HEMIJSKA INDUSTRIJA, 2007, 61 (01) : 13 - 17
  • [45] Reduction of p-nitrotoluene by aqueous ammonium sulfide:: Anion exchange resin as a triphasic catalyst
    Maity, Sunil K.
    Pradhan, Narayan C.
    Patwardhan, Anand V.
    CHEMICAL ENGINEERING JOURNAL, 2008, 141 (1-3) : 187 - 193
  • [46] Kinetics study on esterification of acrylic acid and ethanol over acidic cation-exchange resin beads Amberlyst 35
    Lin, Jer-Wei
    Zaki, A. H.
    Wu, Hsien-Tsung
    Lin, Ho-mu
    Lee, Ming-Jer
    JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2019, 102 : 44 - 50
  • [47] Esterification of methacrylic acid with epichlorohydrin over syringic acid functionalized mesoporous silica nanocomposites
    Dubey, Amit
    Gourav, P. B.
    Singh, Harjinder
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2025, : 1439 - 1451
  • [48] Transesterification of propylene glycol methyl ether in chromatographic reactors using anion exchange resin as a catalyst
    Oh, Jungmin
    Sreedhar, Balamurali
    Donaldson, Megan E.
    Frank, Timothy C.
    Schultz, Alfred K.
    Bommarius, Andreas S.
    Kawajiri, Yoshiaki
    JOURNAL OF CHROMATOGRAPHY A, 2016, 1466 : 84 - 95
  • [49] Esterification of free fatty acid in used cooking oil using gelular exchange resin as catalysts
    Yunus, Nursofia Binti Mohd
    Roslan, Nurul Asmawati Binti
    Yee, Chin Sim
    Abidin, Sumaiya Zainal
    PROCEEDING OF 4TH INTERNATIONAL CONFERENCE ON PROCESS ENGINEERING AND ADVANCED MATERIALS (ICPEAM 2016), 2016, 148 : 1274 - 1281
  • [50] Kinetics of the esterification of palmitic acid with methanol catalyzed by 12-tungstophosphoric acid supported on ZrO2
    K. Srilatha
    N. Lingaiah
    P. S. Sai Prasad
    B. L. A. Prabhavathi Devi
    R. B. N. Prasad
    Reaction Kinetics, Mechanisms and Catalysis, 2011, 104 : 211 - 226
12345