Esterification of palmitic acid with epichlorohydrin on anion exchange resin catalyst

被引：7
|
作者：
Muresan, Emil Ioan
Oprea, Spiridon
Malutan, Theodor
Vata, Mihai
机构：
[1] Gh Asachi Tech Univ Iassy, Fac Chem Engn, Dept Organ & Biochem Engn, Iasi 700050, Romania
[2] Gh Asachi Tech Univ Iassy, Fac Chem Engn, Dept Nat & Synthet Polymers, Iasi 700050, Romania
来源：
CENTRAL EUROPEAN JOURNAL OF CHEMISTRY | 2007年 / 5卷 / 03期
关键词：
palmitic acid; epichlorohydrin; esterification; kinetics; ion exchange resins;
D O I：
10.2478/s11532-007-0033-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The esterification reaction of palmitic acid with epichlorohydrin catalyzed by an anionic macroporous resin was studied. Purolite A-500 resin proved to be a very effective catalyst in the synthesis of 3-chloro-2-hydroxypropyl palmitate. The effects of certain parameters such as speed of agitation, catalyst particle size, catalyst loading, temperature, initial molar ratio between reactants on the rate of reaction were studied. It was found that the overall rate is intrinsically kinetically controlled. The structure of synthesized ester was confirmed by FTIR and H-1 NMR analyses. (c) Versita Warsaw and Springer-Verlag Berlin Heidelberg. All rights reserved.
引用
收藏
页码：715 / 726
页数：12
相关论文
共 50 条
  • [21] Kinetics of esterification of acetic acid and methanol using Amberlyst 36 cation-exchange resin solid catalyst
    Mekala, Mallaiah
    Goli, Venkat Reddy
    PROGRESS IN REACTION KINETICS AND MECHANISM, 2015, 40 (04) : 367 - 382
  • [22] Esterification of oleic acid in a three-phase, fixed-bed reactor packed with a cation exchange resin catalyst
    Son, Sung Mo
    Kimura, Hiroko
    Kusakabe, Katsuki
    BIORESOURCE TECHNOLOGY, 2011, 102 (02) : 2130 - 2132
  • [23] The synthesis of sulphonated hypercrosslinked exchange resin for free fatty acid esterification
    Roslan, Nurul Asmawati
    Abdullah, Norhayati
    Abidin, Sumaiya Zainal
    COMPTES RENDUS CHIMIE, 2019, 22 (11-12) : 761 - 770
  • [24] Kinetic study for esterification of lactic acid with ethanol and hydrolysis of ethyl lactate using an ion-exchange resin catalyst
    Delgado, Patricia
    Sanz, Maria Teresa
    Beltran, Sagrario
    CHEMICAL ENGINEERING JOURNAL, 2007, 126 (2-3) : 111 - 118
  • [25] Kinetics of the esterification of palmitic acid with methanol catalyzed by 12-tungstophosphoric acid supported on ZrO2
    Srilatha, K.
    Lingaiah, N.
    Prasad, P. S. Sai
    Devi, B. L. A. Prabhavathi
    Prasad, R. B. N.
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2011, 104 (01) : 211 - 226
  • [26] Determination of Steric Effect on the Esterification of Different Alcohols with Propanoic Acid over Cation-exchange Resin Catalyst Dowex 50Wx4
    Erdem, Beyhan
    Cebe, Mustafa
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2011, 225 (01): : 125 - 136
  • [27] A kinetic study of the aldol condensation of acetone using an anion exchange resin catalyst
    Podrebarac, GG
    Ng, FTT
    Rempel, GL
    CHEMICAL ENGINEERING SCIENCE, 1997, 52 (17) : 2991 - 3002
  • [28] A novel highly acidic sulfonic functionalized SBA-1 cubic mesoporous catalyst and its application in the esterification of palmitic acid
    Abbasi, A.
    Mahjoub, A. Reza
    Badiei, A. R.
    MATERIALS SCIENCE-POLAND, 2010, 28 (02): : 565 - 572
  • [29] Computational Insights into the Esterification of Palmitic Acid with Methanol in Water
    Feng, Yun
    Ma, Yiding
    Yu, Tao
    Li, Jingjiao
    JOURNAL OF OLEO SCIENCE, 2022, 71 (11) : 1655 - 1661
  • [30] Acid exchange resins deactivation in the esterification of free fatty acids
    Tesser, Riccardo
    Di Serio, Martino
    Casale, Luca
    Sannino, Lucio
    Ledda, Marianna
    Santacesaria, Elio
    CHEMICAL ENGINEERING JOURNAL, 2010, 161 (1-2) : 212 - 222
12345