Esterification of palmitic acid with epichlorohydrin on anion exchange resin catalyst

被引：7
|
作者：
Muresan, Emil Ioan
Oprea, Spiridon
Malutan, Theodor
Vata, Mihai
机构：
[1] Gh Asachi Tech Univ Iassy, Fac Chem Engn, Dept Organ & Biochem Engn, Iasi 700050, Romania
[2] Gh Asachi Tech Univ Iassy, Fac Chem Engn, Dept Nat & Synthet Polymers, Iasi 700050, Romania
来源：
CENTRAL EUROPEAN JOURNAL OF CHEMISTRY | 2007年 / 5卷 / 03期
关键词：
palmitic acid; epichlorohydrin; esterification; kinetics; ion exchange resins;
D O I：
10.2478/s11532-007-0033-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The esterification reaction of palmitic acid with epichlorohydrin catalyzed by an anionic macroporous resin was studied. Purolite A-500 resin proved to be a very effective catalyst in the synthesis of 3-chloro-2-hydroxypropyl palmitate. The effects of certain parameters such as speed of agitation, catalyst particle size, catalyst loading, temperature, initial molar ratio between reactants on the rate of reaction were studied. It was found that the overall rate is intrinsically kinetically controlled. The structure of synthesized ester was confirmed by FTIR and H-1 NMR analyses. (c) Versita Warsaw and Springer-Verlag Berlin Heidelberg. All rights reserved.
引用
收藏
页码：715 / 726
页数：12
相关论文
共 50 条
  • [1] Kinetic studies for the esterification of acetic acid with epichlorohydrin over an anion exchange resin catalyst
    Muresan, Emil Ioan
    Oprea, Spiridon
    Hulea, Vasile
    Malutan, Theodor
    Vata, Mihai
    CENTRAL EUROPEAN JOURNAL OF CHEMISTRY, 2008, 6 (03): : 419 - 428
  • [2] STUDIES CONCERNING THE ANION EXCHANGE RESINS CATALYZED ESTERIFICATION OF EPICHLOROHYDRIN WITH ORGANIC ACIDS
    Muresan, Emil Ioan
    Malutan, Teodor
    CHEMICAL INDUSTRY & CHEMICAL ENGINEERING QUARTERLY, 2009, 15 (03) : 169 - 174
  • [3] Epichlorhydrin esterification with acetic acid over anion exchange resins
    Muresan, Emil
    Oprea, Spiridon
    Hulea, Vasile
    Georgescu, Nicolae
    REVISTA DE CHIMIE, 2007, 58 (06): : 574 - 578
  • [4] Esterification of palmitic acid on the ammonium salt of 12-tungstophosphoric acid: The influence of partial proton exchange on the activity of the catalyst
    Giri, BY
    Rao, KN
    Devi, BLAP
    Lingaiah, N
    Suryanarayana, I
    Prasad, RBN
    Prasad, PSS
    CATALYSIS COMMUNICATIONS, 2005, 6 (12) : 788 - 792
  • [5] Esterification of Palm Fatty Acid Distillate with Epychlorohydrin using Cation Exchange Resin Catalyst
    Budhijanto, Budhijanto
    Subagyo, Albertus F. P. H.
    INTERNATIONAL SEMINAR ON FUNDAMENTAL AND APPLICATION OF CHEMICAL ENGINEERING 2016 (ISFACHE 2016), 2017, 1840
  • [6] Esterification of maleic acid and butanol using cationic exchange resin as catalyst
    Aarti Mulay
    V K Rathod
    Journal of Chemical Sciences, 2017, 129 : 1713 - 1720
  • [7] Esterification of maleic acid and butanol using cationic exchange resin as catalyst
    Mulay, Aarti
    Rathod, V. K.
    JOURNAL OF CHEMICAL SCIENCES, 2017, 129 (11) : 1713 - 1720
  • [8] Performance of ion exchange resin as solid catalyst for the esterification of acetic acid with ethanol
    Bamunusingha, B. A. N. N.
    De Silva, E. C. L.
    Gunasekera, M. Y.
    JOURNAL OF THE NATIONAL SCIENCE FOUNDATION OF SRI LANKA, 2016, 44 (01): : 83 - 93
  • [9] Optimization in esterification of palmitic acid with excess methanol by solid acid catalyst
    Dang, Tan-Hiep
    Chen, Bing-Hung
    FUEL PROCESSING TECHNOLOGY, 2013, 109 : 7 - 12
  • [10] ESTERIFICATION OF SALICYLIC ACID USING CO4+ MODIFIED CATION-EXCHANGE RESIN AS CATALYST
    Zhang, Ming
    Zhu, Wen Shuai
    Li, Hua Ming
    Shi, Hua
    Yan, Yong Sheng
    Wang, Zhi Gao
    JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, 2012, 57 (04): : 1477 - 1481
12345