Li intercalation in zirconium dioxide films

被引：7

作者：

Jonsson, AK ^{[1
]}

Mattsson, MS ^{[1
]}

Niklasson, GA ^{[1
]}

机构：

[1] Uppsala Univ, Angstrom Lab, Dept Mat Sci, SE-75121 Uppsala, Sweden

来源：

DEFECTS AND DIFFUSION IN CERAMICS: AN ANNUAL RETROSPECTIVE II | 2000年 / 177-1卷

关键词：

intercalation; GITT; Li diffusion; zirconium dioxide;

D O I：

10.4028/www.scientific.net/DDF.177-178.51

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Electronic and Li ionic conduction in sputtered transparent ZrO2 thin films intercalated with Li ions, have been studied using impedance spectroscopy, isothermal transient ionic current and galvanostatic intermittent titration measurements. The ZrO2 was found to be a mixed electronic and ionic conductor with an electron conductivity two orders of magnitude higher than the Li ion conductivity at low ion concentrations. A lattice gas model was used to study the interactions between the intercalated Li ions. The behavior of the Li chemical diffusion coefficient indicated that the net interaction between the intercalated Li ions is attractive.

引用

页码：51 / 58

页数：8

共 16 条

[1]

Granqvist C. G., 1995, HDB INORGANIC ELECTR

[2] THEORETICAL SOLUTION OF THE TRANSIENT CURRENT EQUATION FOR MOBILE IONS IN A DIELECTRIC FILM UNDER THE INFLUENCE OF A CONSTANT ELECTRIC-FIELD [J].

GREEUW, G ;

HOENDERS, BJ .

JOURNAL OF APPLIED PHYSICS, 1984, 55 (09) :3371-3375

[3] APPLICATION OF AC TECHNIQUES TO THE STUDY OF LITHIUM DIFFUSION IN TUNGSTEN TRIOXIDE THIN-FILMS [J].

HO, C ;

RAISTRICK, ID ;

HUGGINS, RA .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1980, 127 (02) :343-350

[4] HIGH-RATE REACTIVE SPUTTER DEPOSITION OF ZIRCONIUM DIOXIDE [J].

JONES, F .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1988, 6 (06) :3088-3097

[5] Consideration on the potential-composition relationships observed with amorphous intercalation systems such as LixWO3 [J].

Kudo, T ;

Hibino, M .

SOLID STATE IONICS, 1996, 84 (1-2) :65-72

[6] Diffusion coefficients of lithium ions during intercalation into graphite derived from the simultaneous measurements and modeling of electrochemical impedance and potentiostatic intermittent titration characteristics of thin graphite electrodes [J].

Levi, MD ;

Aurbach, D .

JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (23) :4641-4647

[7] MEASUREMENT OF PH IN SUBCRITICAL AND SUPERCRITICAL AQUEOUS SYSTEMS [J].

MACDONALD, DD ;

HETTIARACHCHI, S ;

SONG, H ;

MAKELA, K ;

EMERSON, R ;

BENHAIM, M .

JOURNAL OF SOLUTION CHEMISTRY, 1992, 21 (08) :849-881

[8] Cation intercalation in sputter-deposited W oxide films [J].

Mattsson, MS .

PHYSICAL REVIEW B, 1998, 58 (16) :11015-11022

[9] A frequency response and transient current study of β-Ta2O5:: Methods of estimating the dielectric constant, direct current conductivity, and ion mobility [J].

Mattsson, MS ;

Niklasson, GA ;

Forsgren, K ;

Hårsta, A .

JOURNAL OF APPLIED PHYSICS, 1999, 85 (04) :2185-2191

[10]

MCKINNON WR, 1987, MOD ASPECT ELECTROC, P235

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