The rate constant of the reaction of H• with tert-butyl alcohol in aqueous solution revisited

被引：7
|
作者：
Alam, MS [1 ]
Janata, E [1 ]
机构：
[1] Hahn Meitner Inst Berlin GmbH, Bereich Solarenergieforsch, D-14109 Berlin, Germany
来源：
CHEMICAL PHYSICS LETTERS | 2004年 / 398卷 / 4-6期
关键词：
D O I：
10.1016/j.cplett.2004.09.124
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The rate constant for the reaction of H-. with tert-butyl alcohol in aqueous solution has been re-determined utilizing pulse radiolysis optical measurements. Special care was taken to avoid the formation of isobutene as a competitive species. A value of 1.5 x 10(5) dm(3) mol(-1) s(-1) was thus obtained, which is in good agreement with previous values. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：557 / 559
页数：3
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