Strong reduction of hydroxylamine accumulation in the catalytic hydrogenation of nitroarenes by vanadium promoters

被引：84

作者：

Baumeister, P ^{[1
]}

Blaser, HU

Studer, M

机构：

[1] Novartis Serv AG, Catalysis Serv, CH-4002 Basel, Switzerland

[2] Novartis Serv AG, Synth Serv, CH-4002 Basel, Switzerland

来源：

CATALYSIS LETTERS | 1997年 / 49卷 / 3-4期

关键词：

catalytic hydrogenation; aromatic nitro compounds; nitroarenes; hydroxylamine accumulation; vanadium promoter;

D O I：

10.1023/A:1019034128024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The accumulation of hydroxylamines during the catalytic hydrogenation of several aromatic nitro compounds could be reduced from > 40% to < 1% by the addition of catalytic amounts of vanadium promoters, resulting in a faster reaction and purer products.

引用

页码：219 / 222

页数：4

共 12 条

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Downing, RS
Kunkeler, PJ
vanBekkum, H
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