Iodopropyl-branched polysiloxane gel electrolytes with improved ionic conductivity upon cross-linking

被引：14

作者：

De Gregorio, G. L. ^{[1
]}

Giannuzzi, R. ^{[1
]}

Cipolla, M. P. ^{[1
]}

Agosta, R. ^{[1
]}

Grisorio, R. ^{[2
]}

Capodilupo, A. ^{[3
]}

Suranna, G. P. ^{[2
]}

Gigli, G. ^{[3
,4
]}

Manca, M. ^{[1
]}

机构：

[1] Fdn Ist Italiano Tecnol, Ctr Biomol Nanotechnol, I-73010 Lecce, Italy

[2] Politecn Bari, Dipartimento Ingn Civile Ambientale Terr Edile &, DICATECh, I-70125 Bari, Italy

[3] Distretto Tecnol, CNR, Ist Nanosci, Natl Nanotechnol Lab, I-73100 Lecce, Italy

[4] Univ Salento, Dipartimento Matemat & Fis E De Giorgi, I-73100 Lecce, Italy

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 90期

关键词：

SENSITIZED SOLAR-CELLS; POLY(ETHYLENE OXIDE); COMPLEXES; POLYMER; MORPHOLOGY; IODIDE; POINT;

D O I：

10.1039/c4cc05152a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We here report the implementation of poly[(3-N-methylimidazolium-propyl)methylsiloxane-co-dimethylsiloxane]iodides as suitable polymeric hosts for a novel class of in situ cross-linkable iodine/iodide-based gel-electrolytes for dye-sensitized solar cells. The polymers are first partially quaternized and then subjected to a thermal cross-linking which allows the formation of a 3D polymeric network which is accompanied by a dramatic enhancement of the ionic conductivity.

引用

页码：13904 / 13906

页数：3

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