Accelerator based synthesis of hydroxyapatite by MeV ion implantation

被引:25
作者
Rautray, Tapash R. [1 ,2 ]
Narayanan, R. [1 ,3 ]
Kwon, Tae-Yub [1 ,2 ,3 ]
Kim, Kyo-Han [1 ,2 ,3 ]
机构
[1] Kyungpook Natl Univ, Sch Dent, Dept Dent Biomat, Taegu, South Korea
[2] Kyungpook Natl Univ, Inst Biomat Res & Dev, Taegu, South Korea
[3] Kyungpook Natl Univ, Brain Korea Project 21, Taegu, South Korea
关键词
Ion implantation; MeV ion irradiation; Annealing; Hydroxyapatite; EARLY BONE-FORMATION; TITANIUM SURFACES; CALCIUM; PHOSPHATE; COATINGS;
D O I
10.1016/j.tsf.2009.08.044
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Accelerator based MeV ion implantation of Ca2+ and P2+ into the titanium substrate to form hydroxyapatite (HA) has been carried out. Calcium hydroxide was formed after heating the calcium implanted titanium in air at 80 degrees C for 3 h. Upon subsequent annealing for 5 min at 600 degrees C HA was formed on the surface. Penetration depth of the HA layer in this method is much higher as compared to key ion implantation. By elemental analysis, Ca/P ratio of the HA was found to be 1.76 which is higher than the ideal 1.67. This higher Ca/P ratio is attributed to the higher penetration depth of the MeV technique used. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:3160 / 3163
页数:4
相关论文
共 32 条
[1]  
DEARNALEY PG, 1973, ION IMPLANTATION
[2]   EFFECT OF PARALLEL SURFACE MICROGROOVES AND SURFACE-ENERGY ON CELL-GROWTH [J].
DENBRABER, ET ;
DERUIJTER, JE ;
SMITS, HTJ ;
GINSEL, LA ;
VONRECUM, AF ;
JANSEN, JA .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, 1995, 29 (04) :511-518
[3]   Characterization of titanium surfaces with calcium and phosphate and osteoblast adhesion [J].
Feng, B ;
Weng, J ;
Yang, BC ;
Qu, SX ;
Zhang, XD .
BIOMATERIALS, 2004, 25 (17) :3421-3428
[4]   Evaluating interface strength of calcium phosphate sol-gel-derived thin films to Ti6Al4V substrate [J].
Gan, L ;
Wang, H ;
Pillar, RM .
BIOMATERIALS, 2005, 26 (02) :189-196
[5]   The contribution of coating microstructure to degradation and particle release in hydroxyapatite coated prostheses [J].
Gross, KA ;
Ray, N ;
Rokkum, M .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, 2002, 63 (02) :106-114
[6]   Thin hydroxyapatite coatings via sol-gel synthesis [J].
Gross, KA ;
Chai, CS ;
Kannangara, GSK ;
Ben-Nissan, B ;
Hanley, L .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 1998, 9 (12) :839-843
[7]  
Hanawa T, 1997, J BIOMED MATER RES, V36, P131, DOI 10.1002/(SICI)1097-4636(199707)36:1<131::AID-JBM16>3.3.CO
[8]  
2-G
[9]   Microdissolution of calcium ions from calcium-ion-implanted titanium [J].
Hanawa, T ;
Asami, K ;
Asaoka, K .
CORROSION SCIENCE, 1996, 38 (09) :1579-1594
[10]  
Howlett CR, 1999, J BIOMED MATER RES, V44, P352, DOI 10.1002/(SICI)1097-4636(19990305)44:3<352::AID-JBM14>3.0.CO