Palladium(II) and platinum(II) complexes bearing a κ3SCS pincer ligand with an azulene unit

被引：30

作者：

Kuwabara, Junpei ^{[1
]}

Munezawa, Goro ^{[1
]}

Okamoto, Ken ^{[1
]}

Kanbara, Takaki ^{[1
]}

机构：

[1] Univ Tsukuba, Tsukuba Res Ctr Interdisciplinary Mat Sci TIMS, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058573, Japan

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 27期

关键词：

ORGANOMETALLIC CHEMISTRY; CATALYTIC-ACTIVITY; LAWESSONS REAGENT; ORGANIC-SYNTHESIS; ANION RECEPTORS; SPECTROSCOPY; SCS; AZULIPORPHYRINS; COORDINATION; DERIVATIVES;

D O I：

10.1039/c002908d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel Pd and Pt SCS-pincer complexes with an azulene unit were synthesized from the reaction of a metal precursor with an azulene molecule having two thioamide moieties. The crystal structures of the complexes were confirmed by X-ray diffraction analysis. Their structural and optical properties were investigated in comparison with those of related complexes with a benzene and pyrrole unit by NMR and UV/Vis spectroscopy. DFT calculations for the azulene complexes revealed that the origin of the long-wavelength absorption is assigned to a transition from the metal center to the extended p system of the azulene unit.

引用

页码：6255 / 6261

页数：7

共 51 条

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