An easy access to α,β-unsaturated thioacylsilanes:: a useful route to silylated 1,2-dithins

被引：12

作者：

Capperucci, A ^{[1
]}

Degl'Innocenti, A ^{[1
]}

Biondi, S ^{[1
]}

Nocentini, T ^{[1
]}

Rinaudo, G ^{[1
]}

机构：

[1] ICCOM, Dipartimento Chim Organ, I-50019 Sesto Fiorentino, FI, Italy

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 14期

关键词：

D O I：

10.1016/S0040-4039(03)00445-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of different silylated allenes with hexamethyldisilathiane (HMDST) in the presence of CoCl2.6H(2)O affords an easy and high yielding access to alpha,beta-unsaturated thioacylsilanes, which undergo a self-dimerization reaction to afford polyfunctionalized 1,2-dithiins as the major products. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：2831 / 2835

页数：5

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