Fabrication of 3D MoS2-TiO2@PAN electro-spun membrane for efficient and recyclable photocatalytic degradation of organic dyes

被引:35
作者
Zhang, Xiaoyuan [1 ]
Fu, Kun [1 ]
Su, Zhiqiang [1 ]
机构
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing Key Lab Adv Funct Polymer Composites, Beijing 100029, Peoples R China
来源
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS | 2021年 / 269卷
基金
中国国家自然科学基金;
关键词
Photocatalytic degradation; MoS2; nanosheets; TiO2; nanotubes; PAN electrospun membrane; MOS2; TIO2; NANOCOMPOSITE; NANOPARTICLES; CARBON; WATER; PHOTODEGRADATION; HETEROSTRUCTURES; CONSTRUCTION; PERFORMANCE;
D O I
10.1016/j.mseb.2021.115179
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this work, molybdenum disulfide-titanium dioxide (MoS2-TiO2) nanohybrids were decorated on polyacrylonitrile (PAN) electrospun membrane to fabricate a highly efficient and recyclable 3D composite for photocatalytic degradation of organic pollutants. It was found that the high surface area of MoS2 nanosheets facilitated the formation of TiO2 nanotubes, which further promoted the exfoliation of MoS2 nanosheets. In addition, the matched band gaps between MoS2 nanosheets and TiO2 nanotubes brought MoS2-TiO2@PAN membrane excellent photocatalytic degradation performance of five organic dyes. The best degradation efficiency of the as-prepared MoS2-TiO2@PAN membrane was 97.73%. Based on these results, we presented the photocatalytic degradation mechanism of MoS2-TiO2@PAN membrane. Our strategy for fabricating efficient and recyclable 3D MoS2-TiO2@PAN membrane is facile, cost-efficient and eco-friendly, which will be a promising method for the photocatalytic degradation of organic dyes.
引用
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页数:9
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共 52 条
[1]   Lithium-ion intercalation into TiO2-B nanowires [J].
Armstrong, AR ;
Armstrong, G ;
Canales, J ;
García, R ;
Bruce, PG .
ADVANCED MATERIALS, 2005, 17 (07) :862-+
[2]   XPS investigation of preferential sputtering of S from MoS2 and determination of MoSx stoichiometry from Mo and S peak positions [J].
Baker, MA ;
Gilmore, R ;
Lenardi, C ;
Gissler, W .
APPLIED SURFACE SCIENCE, 1999, 150 (1-4) :255-262
[3]   Synthesis of water-soluble dye-cored poly(amidoamine) dendrimers for long-term live cell imaging [J].
Cai, Yang ;
Ji, Chendong ;
Zhang, Shaobo ;
Su, Zhiqiang ;
Yin, Meizhen .
SCIENCE CHINA-MATERIALS, 2018, 61 (11) :1475-1483
[4]   Single-layer MoS2/graphene dispersed in amorphous carbon: towards high electrochemical performances in rechargeable lithium ion batteries [J].
Chang, Kun ;
Chen, Weixiang .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (43) :17175-17184
[5]   Graphene-like MoS2/amorphous carbon composites with high capacity and excellent stability as anode materials for lithium ion batteries [J].
Chang, Kun ;
Chen, Weixiang ;
Ma, Lin ;
Li, Hui ;
Li, He ;
Huang, Feihe ;
Xu, Zhude ;
Zhang, Qingbo ;
Lee, Jim-Yang .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (17) :6251-6257
[6]   Preparation of MoS2/TiO2 based nanocomposites for photocatalysis and rechargeable batteries: progress, challenges, and perspective [J].
Chen, Biao ;
Meng, Yuhuan ;
Sha, Junwei ;
Zhong, Cheng ;
Hua, Wenbin ;
Zhao, Naiqin .
NANOSCALE, 2018, 10 (01) :34-68
[7]   Constructing Hierarchical Spheres from Large Ultrathin Anatase TiO2 Nanosheets with Nearly 100% Exposed (001) Facets for Fast Reversible Lithium Storage [J].
Chen, Jun Song ;
Tan, Yi Ling ;
Li, Chang Ming ;
Cheah, Yan Ling ;
Luan, Deyan ;
Madhavi, Srinivasan ;
Boey, Freddy Yin Chiang ;
Archer, Lynden A. ;
Lou, Xiong Wen .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (17) :6124-6130
[8]   Effect of γ-irradiation on adsorption and photocatalytic ability of MoS2 nanomaterials [J].
He, Yupu ;
Xiang, Xia ;
Sun, Lijie ;
Tian, Chengxiang ;
Yang, Guixia ;
Zu, Xiaotao .
INTERNATIONAL JOURNAL OF MODERN PHYSICS B, 2019, 33 (24)
[9]   Effect of brookite phase on the anatase-rutile transition in titania nanoparticles [J].
Hu, Y ;
Tsai, HL ;
Huang, CL .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2003, 23 (05) :691-696
[10]   Effective visible light-activated B-Doped and B,N-Codoped TiO2 photocatalysts [J].
In, Suil ;
Orlov, Alexander ;
Berg, Regina ;
Garcia, Felipe ;
Pedrosa-Jimenez, Sergio ;
Tikhov, Mintcho S. ;
Wright, Dominic S. ;
Lambert, Richard M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (45) :13790-+