Relationship between the presence of alloy elements and growth mechanisms of oxide layers formed on AISI-430 stainless steels - Influence of Mn, Al and Ti

被引：9

作者：

Berthier, C ^{[1
]}

Lameille, JM

Lenglet, M

Abida, D

Lopitaux, J

Beucher, E

机构：

[1] CENS, CEA, DCC,DPE,SPEA, LESIM,SAIS, F-91191 Gif Sur Yvette, France

[2] Univ Rouen, IUT, LASTSM, F-76821 Mt St Aignan, France

[3] CRITT, F-27100 Val De Reuil, France

来源：

HIGH TEMPERATURE CORROSION AND PROTECTION OF MATERIALS 4, PTS 1 AND 2 | 1997年 / 251-2卷

关键词：

oxidation; manganese; titanium; aluminium; AISI 430 and AISI 430 Al-Ti alloys; oxide-scale morphology;

D O I：

10.4028/www.scientific.net/MSF.251-254.89

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The isothermal oxidation behavior of two commercial stainless steels (AISI 430 and AISI 430 Al-Ti) has been investigated in the temperature range from 800 degrees C to 1000 degrees C in air using grazing incidence XRD, XPS, SEM-EDS and FTIR reflectance spectroscopy. The oxidation mechanism of the AISI 430 alloy is mainly controlled by the outward manganese diffusion in agreement with Grabke's study (Oxidation of Metals, 37 (1992) 81) and induces the formation of a duplex scale : Mn1+xCr2-x-yFeyO4/Cr2O3/alloy. The oxidation of the AISI 430 AI-Ti alloy leads to the formation of a mixture of three main constituents : (CrFe)(2)O-3, TiO2 and Al2O3 (at 1000 degrees C, different mixed titanium oxides are observed : Fe2Ti3O9 and Cr2TiO5). Titanium can diffuse more rapidly than manganese across the initial scale.

引用

页码：89 / 95

页数：7

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