Design and Characterization of Host Frameworks for Facile Magnesium Transport

被引：13

作者：

Gao, Yirong ^{[1
]}

Mishra, Tara P. ^{[2
,3
]}

Bo, Shou-Hang ^{[1
,4
]}

Gautam, Gopalakrishnan Sai ^{[5
]}

Canepa, Pieremanuele ^{[2
,3
,6
]}

机构：

[1] Shanghai Jiao Tong Univ, Univ Michigan Shanghai Jiao Tong Univ Joint Inst, Shanghai, Peoples R China

[2] Natl Univ Singapore, Dept Mat Sci & Engn, Singapore, Singapore

[3] Singapore MIT Alliance Res & Technol, Singapore, Singapore

[4] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai, Peoples R China

[5] Indian Inst Sci, Dept Mat Engn, Bangalore, Karnataka, India

[6] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore, Singapore

来源：

ANNUAL REVIEW OF MATERIALS RESEARCH | 2022年 / 52卷

基金：

新加坡国家研究基金会;

关键词：

ion transport; host frameworks; characterization; magnesium batteries; PROTONIC CONDUCTOR CSH2PO4; STATE NMR-SPECTROSCOPY; 1ST-PRINCIPLES CALCULATIONS; ELECTRONIC CONDUCTIVITY; INTERFACE STABILITY; SOLID ELECTROLYTES; CATHODE MATERIALS; MG INTERCALATION; GRAIN-BOUNDARIES; DIFFUSION;

D O I：

10.1146/annurev-matsci-081420-041617

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The development of inexpensive batteries based on magnesium (Mg) chemistry will contribute remarkably toward developing high-energy-density storage systems that can be used worldwide. Significant challenges remain in developing practical Mg batteries, the chief of which is designing materials that can provide facile transport of Mg. In this review, we cover the experimental and theoretical methods that can be used to quantify Mg mobility in a variety of host frameworks, the specific transport quantities that each technique is designed to measure or calculate, and some practical examples of their applications. We then list the unique challenges faced by different experimental and computational techniques in probing Mg ion transport in materials. This review concludes with an outlook on the directions that the scientific community could soon pursue as we strive to construct a pragmatic Mg battery.

引用

页码：129 / 158

页数：30

共 147 条

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