Asymmetric autocatalysis induced by chiral hydrocarbon [2.2]paracyclophanes

被引：18
|
作者：
Sato, I [1 ]
Ohno, A [1 ]
Aoyama, Y [1 ]
Kasahara, T [1 ]
Soai, K [1 ]
机构：
[1] Tokyo Univ Sci, Dept Appl Chem, Fac Sci, Shinjuku Ku, Tokyo 1628601, Japan
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2003年 / 1卷 / 02期
关键词：
D O I：
10.1039/b209520n
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Chiral hydrocarbon [2.2]paracyclophanes act as chiral initiators in asymmetric autocatalysis in the addition of diisopropylzinc to pyrimidine-5-carbaldehyde and give highly enantiomerically enriched 5-pyrimidyl alkanol with a reversed sense of the enantioselectivity to that of other [2.2]paracyclophanes with heteroatoms.
引用
收藏
页码：244 / 246
页数：3
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