Near-Linear Controllable Synthesis of Mesoporosity in Hierarchical UiO-66 by Template-Free Nucleation-Competition

被引：40

作者：

Li, Jia-Xin ^{[1
,2
,3
,4
]}

Chang, Gang-Gang ^{[1
,2
,3
,4
]}

Tian, Ge ^{[1
,2
,3
,4
]}

Pu, Chun ^{[1
,2
,3
,4
]}

Huang, Ke-Xin ^{[1
,2
,3
,4
]}

Ke, Shan-Chao ^{[1
,2
,3
,4
]}

Janiak, Christoph ^{[5
]}

Yang, Xiao-Yu ^{[1
,2
,3
,4
,6
]}

机构：

[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, 122 Luoshi Rd, Wuhan 430070, Hubei, Peoples R China

[2] Wuhan Univ Technol, Sch Chem Chem Engn & Life Sci, 122 Luoshi Rd, Wuhan 430070, Hubei, Peoples R China

[3] Wuhan Univ Technol, Sch Mat Sci & Engn, 122 Luoshi Rd, Wuhan 430070, Hubei, Peoples R China

[4] Wuhan Univ Technol, Int Sch Mat Sci & Engn, 122 Luoshi Rd, Wuhan 430070, Hubei, Peoples R China

[5] Heinrich Heine Univ Dusseldorf, Inst Anorgan Chem & Strukturchem, D-40204 Dusseldorf, Germany

[6] Harvard Univ, Sch Engn & Appl Sci, Cambridge, MA 02138 USA

来源：

ADVANCED FUNCTIONAL MATERIALS | 2021年 / 31卷 / 30期

基金：

中国国家自然科学基金;

关键词：

angiogenesis; anti-inflammation activity; diabetic wound repair; macrophages polarization; multifunctional bioactive scaffolds; GRAPHENE OXIDE SCAFFOLDS; ANTIBACTERIAL; MACROPHAGES; RESPONSES; REPAIR;

D O I：

10.1002/adfm.202102868

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hierarchies design of porosity in metal-organic frameworks (MOFs) has gained significant interest in recent years, and customization of mesoporous sizes in MOFs is still quite challenging. Herein, a template-free method by nucleation-competition has been developed to realize a near-linear control of the mesopore sizes (3-13 nm) in the hierarchical MOF UiO-66(Hf). High selectivity of enzyme adsorption, high activity of bulky-molecular catalysis, high stability of mesostructure, and extension to other MOFs further prove the success in the potential customization synthesis and applications.

引用

页数：25

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