One-step ratiometric fluorescence sensing of ascorbic acid in food samples by carbon dots-referenced lanthanide probe

被引:14
作者
Tian, Xiaolin [1 ]
Fan, Zhefeng [1 ]
机构
[1] Shanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Shanxi, Peoples R China
关键词
Food analysis; Lanthanide probe; Carbon dots; Ascorbic acid; Ratiometric fluorescence sensor; QUANTUM DOTS; SELECTIVE DETECTION; LIVING CELLS; VITAMIN-C; FE3+ ION; NANOPARTICLES; NANOPROBE; FACILE; SENSOR; WATER;
D O I
10.1016/j.jphotochem.2021.113261
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report a ratiometric fluorescence sensor formed via the self-assembly of the lanthanide ion Eu3+ and blueemitting carbon dots (CDs) for the direct detection of ascorbic acid (AA). The obtained sensor exhibited the characteristic emission of 2,6-pyridinedicarboxylic acid (DPA)-sensitized Eu3+ (Eu?DPA) at 615 nm and the weak emission of CDs at 440 nm under excitation at 283 nm. After the addition of AA, the fluorescence emission of Eu?DPA, which served as the AA recognition site, was significantly quenched, whereas the emission of CDs changed slightly, resulting in a ratiometric fluorescent response toward AA. A wide linear range from 0.5 ?M to 820 ?M was achieved in the detection of AA with an LOD of 60 nM. Moreover, this CDs/Eu?DPA sensor, which displayed excellent sensitivity and selectivity, was successfully applied for the determination of AA in fruits, vegetables and beverage samples, suggesting a great potential for applications in foods.
引用
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页数:7
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