Formation of 1,4-diketones by aerobic oxidative C-C coupling of styrene with 1,3-dicarbonyl compounds

被引：58
|
作者：
Rössle, M [1 ]
Werner, T [1 ]
Baro, A [1 ]
Frey, W [1 ]
Christoffers, J [1 ]
机构：
[1] Univ Stuttgart, Inst Organ Chem, D-70569 Stuttgart, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 47期
关键词：
dicarbonyl compounds; C-C coupling; cerium; heterocycles; homogeneous catalysis;
D O I：
10.1002/anie.200461406
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical equation presented). Convenient and direct: 1,4-Dicarbonyl compounds are readily obtained through a one-pot cerium-catalyzed oxidative C-C coupling in the presence of oxygen and subsequent fragmentation. The products are suitable precursors for heterocycles.
引用
收藏
页码：6547 / 6549
页数：3
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