A simple equation for the solubility of a solid in a supercritical fluid cosolvent with a gas or another supercritical fluid

被引：3

作者：

Ruckenstein, E ^{[1
]}

Shulgin, I ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem Engn, Amherst, NY 14260 USA

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2003年 / 42卷 / 05期

关键词：

D O I：

10.1021/ie020871c

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A simple equation for calculating the solubilities of solid substances in gaseous mixtures of a supercritical fluid with another supercritical one or an inert gas was derived. This equation involves only the solubilities of the solid in the individual constituents of the gaseous mixture and the molar volumes of the latter. The equation was tested for the solubilities of naphthalene, benzoic acid, caffeine, cholesterol, and soybean oil in gaseous mixtures containing at least one supercritical fluid. In all cases good agreement with experimental data was found.

引用

页码：1106 / 1110

页数：5

共 27 条

[1] High-pressure PVT behavior of natural fats and oils, trilaurin, triolein, and n-tridecane from 303 K to 353 K from atmospheric pressure to 150 MPa [J].