Nitrogen and Sulfur Co-Doped Graphene Quantum Dots Anchored TiO2 Nanocomposites for Enhanced Photocatalytic Activity

Herein, nitrogen (N) and sulfur (S) co-doped graphene quantum dots (GQDs) using different one-dimensional (1-D) carbon nanomaterials as precursors were synthesized, followed by heterojunction formation with TiO2. GQDs exhibit unlike physiochemical properties due to the disproportionate ratio of N and S heteroatoms and dissimilar reaction parameters. Tailored type-II band gap (E-g) alignment was formed with narrowed E-g value that improves photogenerated electron transfer due to pi-conjugation. GQDs-TiO2 nanocomposites exhibit remarkably high methylene blue (MB) degradation up to 99.78% with 2.3-3 times elevated rate constants as compared with TiO2. CNF-GQDs-TiO2 demonstrates the fastest MB degradation (60 min) due to the synergistic effect of nitrogen and sulfur doping, and is considered the most stable photocatalyst among prepared nanocomposites as tested up to three cyclic runs. Whereas, C-O-Ti bonds were not only responsible for nanocomposites strengthening but also provide a charge transfer pathway. Moreover, charge transport behavior, generation of active species, and reaction mechanism were scrutinized via free-radical scavenger analysis.