Catalytic Epoxidation of 3-Carene and Limonene with Aqueous Hydrogen Peroxide, and Selective Synthesis of α-Pinene Epoxide from Turpentine

被引：5

作者：

Fomenko, Vladislav V. ^{[1
]}

Laev, Sergey S. ^{[1
]}

Salakhutdinov, Nariman F. ^{[1
]}

机构：

[1] RAS, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, 9 Lavrentiev Ave, Novosibirsk 630090, Russia

来源：

CATALYSTS | 2021年 / 11卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

epoxidation; turpentine; α -pinene; -pinene epoxide; 3-carene; 3-carene epoxide; limonene; limonene diepoxide; aqueous hydrogen peroxide;

D O I：

10.3390/catal11040436

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The epoxidation of turpentine (technical alpha-pinene), 3-carene, and limonene with aqueous hydrogen peroxide was studied in a new catalytic system employing manganese sulfate, salicylic acid, sodium bicarbonate, and acetonitrile, as a polar solvent. The proposed approach makes it possible to carry out a "chemical separation" of turpentine components, yielding valuable individual derivatives of monoterpenes without the need to isolate individual monoterpene reagents. Specific methods have been developed for the production of alpha-pinene epoxide, 3-carene epoxide, limonene diepoxide, as well as for two related compounds: 3-carene-5-one and 3-carene-2,5-dione.

引用

页数：8

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