Catalytic Epoxidation of 3-Carene and Limonene with Aqueous Hydrogen Peroxide, and Selective Synthesis of α-Pinene Epoxide from Turpentine

被引:5
作者
Fomenko, Vladislav V. [1 ]
Laev, Sergey S. [1 ]
Salakhutdinov, Nariman F. [1 ]
机构
[1] RAS, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, 9 Lavrentiev Ave, Novosibirsk 630090, Russia
基金
俄罗斯基础研究基金会;
关键词
epoxidation; turpentine; α -pinene; -pinene epoxide; 3-carene; 3-carene epoxide; limonene; limonene diepoxide; aqueous hydrogen peroxide;
D O I
10.3390/catal11040436
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The epoxidation of turpentine (technical alpha-pinene), 3-carene, and limonene with aqueous hydrogen peroxide was studied in a new catalytic system employing manganese sulfate, salicylic acid, sodium bicarbonate, and acetonitrile, as a polar solvent. The proposed approach makes it possible to carry out a "chemical separation" of turpentine components, yielding valuable individual derivatives of monoterpenes without the need to isolate individual monoterpene reagents. Specific methods have been developed for the production of alpha-pinene epoxide, 3-carene epoxide, limonene diepoxide, as well as for two related compounds: 3-carene-5-one and 3-carene-2,5-dione.
引用
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页数:8
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