Graphene/polyphenylene sulfide composites for tailorable negative permittivity media by plasmonic oscillation

被引:16
作者
Fan, Guohua [1 ]
Shi, Guangyue [1 ]
Ren, Huan [1 ]
Liu, Yao [1 ]
Fan, Runhua [2 ]
机构
[1] Shandong Univ, Minist Educ, Key Lab Liquid Solid Struct Evolut & Proc Mat, Jinan 250061, Shandong, Peoples R China
[2] Shanghai Maritime Univ, Coll Ocean Sci & Engn, Shanghai 201306, Peoples R China
基金
中国国家自然科学基金;
关键词
Polymeric composites; Dielectrics; Percolation; Negative permittivity; POLYMER COMPOSITES; CARBON NANOTUBES; GRAPHENE; METACOMPOSITES; PERFORMANCE; BEHAVIOR; FIBERS;
D O I
10.1016/j.matlet.2019.126683
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Composites with negative permittivity have drawn much attentions for novel capacitance design and electromagnetic shielding applications. Herein, polyphenylene sulfide (PPS) matrix composites filled with graphene were prepared by hot-pressing for tailorable negative permittivity media. Electrical percolation occurred as graphene content increasing and the conduction mechanism changed into free electron model. Graphene/PPS composites with tailorable negative permittivity properties were realized, resulting from the plasmonic oscillation of free electrons in composites exceeding percolation threshold. The regulation mechanism of negative permittivity in this random composite was clarified, and the obtained tailorable negative permittivity media could be novel candidates for various electromagnetic applications. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页数:4
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