Rational Extension of the Family of Layered, Covalent, Triazine-Based Frameworks with Regular Porosity

被引：504

作者：

Bojdys, Michael J. ^{[1
]}

Jeromenok, Jekaterina ^{[1
]}

Thomas, Arne ^{[2
]}

Antonietti, Markus ^{[1
]}

机构：

[1] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14476 Potsdam, Germany

[2] Tech Univ Berlin, D-10587 Berlin, Germany

来源：

ADVANCED MATERIALS | 2010年 / 22卷 / 19期

关键词：

HALOGENATION; CRYSTALLINE; POLYMERS; CARBON;

D O I：

10.1002/adma.200903436

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A layered, covalent, triazine-based framework (CTF) was synthesized via the condensation of 2,6-naphthalenedicarbonitrile under ionothermal conditions. The polytrimerization of this bi functional carbon nitrile in zinc chloride at lower temperatures yields a well-ordered, close-packed framework. At elevated temperatures an amorphous, yet porous solid is obtained, which shows remarkable thermal stability (640 degrees C) and a high surface area (2255 m(2) g(-1) and 1.51 cm(3) g(-1)).

引用

页码：2202 / +

页数：5

共 23 条

[1] Inorganic crystal engineering using self-assembly of tailored building-blocks [J].

Blake, AJ ;

Champness, NR ;

Hubberstey, P ;

Li, WS ;

Withersby, MA ;

Schröder, M .

COORDINATION CHEMISTRY REVIEWS, 1999, 183 :117-138

[2] Ionothermal Synthesis of Crystalline, Condensed, Graphitic Carbon Nitride [J].

Bojdys, Michael J. ;

Mueller, Jens-Oliver ;

Antonietti, Markus ;

Thomas, Arne .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (27) :8177-8182

[3] SEMICONDUCTOR NANOCRYSTALS COVALENTLY BOUND TO METAL-SURFACES WITH SELF-ASSEMBLED MONOLAYERS [J].

COLVIN, VL ;

GOLDSTEIN, AN ;

ALIVISATOS, AP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (13) :5221-5230

[4] Porous, crystalline, covalent organic frameworks [J].

Côté, AP ;

Benin, AI ;

Ockwig, NW ;

O'Keeffe, M ;

Matzger, AJ ;

Yaghi, OM .

SCIENCE, 2005, 310 (5751) :1166-1170

[5] Fuzzy nanoassemblies: Toward layered polymeric multicomposites [J].

Decher, G .

SCIENCE, 1997, 277 (5330) :1232-1237

[6] Designed synthesis of 3D covalent organic frameworks [J].

El-Kaderi, Hani M. ;

Hunt, Joseph R. ;

Mendoza-Cortes, Jose L. ;

Cote, Adrien P. ;

Taylor, Robert E. ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2007, 316 (5822) :268-272

[7] Hybrid porous solids:: past, present, future [J].

Ferey, Gerard .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214

[8] PHYSICAL ADSORPTION ON NON-UNIFORM SURFACES [J].

HALSEY, G .

JOURNAL OF CHEMICAL PHYSICS, 1948, 16 (10) :931-937

[9] THERMAL STABILITY OF ORGANIC COMPOUNDS [J].

JOHNS, IB ;

SMITH, JO ;

MCELHILL, EA .

INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1962, 1 (01) :2-&

[10]

Kim YH, 1998, J POLYM SCI POL CHEM, V36, P1685, DOI 10.1002/(SICI)1099-0518(199808)36:11<1685::AID-POLA1>3.3.CO

← 1 2 3 →