High resolution core level spectroscopy of hydrogen-terminated (100) diamond

被引:19
|
作者
Schenk, A. K. [1 ]
Rietwyk, K. J. [2 ]
Tadich, A. [1 ,3 ]
Stacey, A. [4 ]
Ley, L. [1 ,5 ]
Pakes, C. I. [1 ]
机构
[1] La Trobe Univ, La Trobe Inst Mol Sci, Dept Chem & Phys, Bundoora, Vic 3086, Australia
[2] Bar Ilan Univ, Ctr Nanotechnol & Adv Mat, Dept Chem, IL-5290002 Ramat Gan, Israel
[3] Australian Synchrotron, 800 Blackburn Rd, Clayton, Vic 3168, Australia
[4] Univ Melbourne, Ctr Quantum Computat & Commun Technol, Sch Phys, Melbourne, Vic 3010, Australia
[5] Univ Erlangen Nurnberg, Inst Tech Phys, Staudtstr 1, D-91058 Erlangen, Germany
基金
澳大利亚研究理事会;
关键词
photoelectron spectroscopy; hydrogen-terminated diamond; diamond (100) surface; X-RAY PHOTOEMISSION; ABSORPTION FINE-STRUCTURE; SINGLE-CRYSTAL; SURFACE; SPECTRA; ORIGIN;
D O I
10.1088/0953-8984/28/30/305001
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Synchrotron-based photoelectron spectroscopy experiments are presented that address a long standing inconsistency in the treatment of the C1s core level of hydrogen terminated (1 0 0) diamond. Through a comparison of surface and bulk sensitive measurements we show that there is a surface related core level component to lower binding energy of the bulk diamond component; this component has a chemical shift of -0.16 +/- 0.05 eV which has been attributed to carbon atoms which are part of the hydrogen termination. Additionally, our results indicate that the asymmetry of the hydrogen terminated (1 0 0) diamond C1s core level is an intrinsic aspect of the bulk diamond peak which we have attributed to sub-surface carbon layers.
引用
收藏
页数:12
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