Kondo effect and thermoelectric transport in CePd3Bex

被引:9
|
作者
Gumeniuk, Roman [1 ,2 ]
Schnelle, Walter [2 ]
Kvashnina, Kristina O. [3 ,4 ]
Leithe-Jasper, Andreas [2 ]
机构
[1] Tech Univ Bergakad Freiberg, Inst Expt Phys, Leipziger Str 23, D-09596 Freiberg, Germany
[2] Max Planck Inst Chem Phys Fester Stoffe, Nothnitzer Str 40, D-01187 Dresden, Germany
[3] ESRF, 71 Ave Martyrs, Grenoble, France
[4] HZDR, Inst Resource Ecol, POB 510119, D-01314 Dresden, Germany
关键词
crystal structure; Kondo effect; thermoelectricity; XAS; X-RAY-ABSORPTION; MAGNETIC-SUSCEPTIBILITY; INTERMEDIATE VALENCE; BEHAVIOR; SPECTROSCOPY; DEPENDENCE; STATE; POWER; HEAT; CE;
D O I
10.1088/0953-8984/28/16/165603
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The physical properties of the series CePd3Bex (0 <= x <= 0.47) have been studied. Introducing Be into CePd3 results in a drastic reduction of the Seebeck coefficient from 100 mu V K-1 at 300 K to -2 mu V K-1, respectively. Paramagnetism of Ce3+ free ions and metallic conduction dominate the physical properties. A structural transition at x = 0.25 is accompanied by a significant lowering of the Kondo temperature and leads to a successive suppression of the thermoelectric performance of CePd3Bex with increasing x.
引用
收藏
页数:8
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