Synthesis, Crystal Structure, and Luminescence of a Three-Dimensional Supramolecular Compound Based on a Dinuclear Tin Cluster

被引：11

作者：

Chai, Wenxiang ^{[1
]}

Song, Li ^{[2
]}

Shen, Hangyan ^{[1
]}

Shu, Kangying ^{[1
]}

机构：

[1] China Jiliang Univ, Coll Mat Sci & Engn, Hangzhou 310018, Zhejiang, Peoples R China

[2] Zhejiang Sci Tech Univ, Key Lab Adv Text Mat & Mfg Technol, Dept Chem, Educ Minist, Hangzhou, Zhejiang, Peoples R China

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2009年 / 184卷 / 12期

基金：

中国国家自然科学基金;

关键词：

Crystal structure; dinuclear tin cluster; hydrogen bonding; supramolecular; pi-pi stacking; MOLECULAR-STRUCTURE; FRAMEWORKS;

D O I：

10.1080/10426500902839400

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A three-dimensional (3D) supramolecular compound, [(phen)LSnS](2)center dot(H2O)(2) (phen = 1,10-phenanthroline, L = mercaptoacetic acid), has been synthesized and the crystal structure was determined by a single crystal X-ray diffraction study. 1 is triclinic, space group P-1 with a = 6.695(1) angstrom, b = 10.929(2) angstrom, c = 12.117(2) angstrom, alpha = 114.55(3)degrees, beta = 93.53(2)degrees, gamma = 104.06(3)degrees, and Z = 1. The dinuclear cluster of [(phen)LSnS](2) and H2O are linked into a 3D supramolecular framework by a combination of O-H center dot center dot center dot O, C-H center dot center dot center dot O hydrogen bonds and pi-pi stacking interactions. Its luminescence property is discussed.

引用

页码：3212 / 3220

页数：9

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