Evaluation of nanocrystalline Sn3N4 derived from ammonolysis of Sn(NEt2)4 as a negative electrode material for Li-ion and Na-ion batteries

被引：48

作者：

Li, Xianji ^{[1
]}

Hector, Andrew L. ^{[1
]}

Owen, John R. ^{[1
]}

Shah, S. Imran U. ^{[1
]}

机构：

[1] Univ Southampton, Chem, Southampton SO17 1BJ, Hants, England

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2016年 / 4卷 / 14期

基金：

英国工程与自然科学研究理事会;

关键词：

CHEMICAL-VAPOR-DEPOSITION; NITRIDE THIN-FILMS; HIGH-CAPACITY; TIN NITRIDE; ANODE MATERIAL; FLUOROETHYLENE CARBONATE; TITANIUM NITRIDE; GRAPHENE OXIDE; SODIUM; LITHIUM;

D O I：

10.1039/c5ta08287k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Bulk nanocrystalline Sn3N4 powders were synthesised by a two step ammonolysis process followed by washing with dilute acid. Their performance as Li-ion and Na-ion battery negative electrodes was assessed by galvanostatic cycling in half cells vs. the metal, giving good performance in both cases and remarkable stability in the sodium cells. The effect of carboxymethyl cellulose and sodium alginate binders was examined and the latter found to give superior performance. Capacity and stability were also enhanced via the use of a fluoroethylene carbonate electrolyte additive.

引用

页码：5081 / 5087

页数：7

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