Molecular magnetism of 3d-transition metals polynuclear complexes

被引:0
|
作者
Pavlyshchuk, VV [1 ]
机构
[1] Natl Acad Sci Ukraine, LV Pysarzhevsky Inst Phys Chem, UA-252039 Kyiv, Ukraine
来源
TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA | 1997年 / 33卷 / 06期
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Various types of polynuclear complexes of 3d-transition metals with S high values in the ground state are considered. Depending on structure and topology of a coordination sphere, various exchange processes occur in these complexes. As a result substances reveal fero-, ferri- and superparamagnetic properties. It has been demonstrated that separate molecules of multispin complexes can display properties, observed earlier only in bulky magnets. Examples of various molecular magnets are considered.
引用
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页码:341 / 361
页数:21
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