Rapid synthesis of Li4Ti5O12/graphene composite with superior rate capability by a microwave-assisted hydrothermal method

被引：76

作者：

Shi, Yi ^{[1
,2
,3
]}

Gao, Jie ^{[1
]}

Abruna, Hector D. ^{[1
]}

Liu, Huakun ^{[2
]}

Li, Huijun ^{[3
]}

Wang, Jiazhao ^{[2
]}

Wu, Yuping ^{[4
,5
]}

机构：

[1] Cornell Univ, Dept Chem & Biol Chem, Ithaca, NY 14853 USA

[2] Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW, Australia

[3] Univ Wollongong, Ctr Electron Microscopy, Wollongong, NSW 2522, Australia

[4] Fudan Univ, Dept Chem, NEML, Shanghai 200433, Peoples R China

[5] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

来源：

NANO ENERGY | 2014年 / 8卷

基金：

澳大利亚研究理事会; 中国国家自然科学基金;

关键词：

Lithium titanate; Lithium ion battery; Graphene; LITHIUM-ION BATTERIES; ANODE MATERIALS; GRAPHENE; PERFORMANCE; CATHODES; NANOSTRUCTURES; NANOSHEETS; CO;

D O I：

10.1016/j.nanoen.2014.06.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Li4Ti5O12 microspheres composed of nanofiakes wrapped in graphene nanosheets have been synthesized by an advanced microwave-hydrothermal (MW-HT) method for the preparation following by an annealing step. Microwave-assisted synthesis processes are appealing, as they can rapidly synthesize materials with a high degree of control of particle size and morphology at low cost. The resultant composite reveals a unique loose structure which could avoid the restacking of graphene sheets and offer rapid lithium ion diffusion paths. Therefore the Li4Ti5O12/graphene electrode has highly desirable properties: a specific capacity approaching the theoretical value, stable cycling, and exceptional rate capability. The composite also can be a good indicator of the remained charge and discharge capacity since it presents a curved charge and discharge line instead of a stable plateau. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：297 / 304

页数：8

共 33 条

[1] Graphene improving lithium-ion battery performance by construction of NiCo2O4/graphene hybrid nanosheet arrays [J].

Chen, Yuejiao ;

Zhu, Jian ;

Qu, Baihua ;

Lu, Bingan ;

Xu, Zhi .

NANO ENERGY, 2014, 3 :88-94

[2] Rapid Synthesis of Li4Ti5O12 Microspheres as Anode Materials and Its Binder Effect for Lithium-Ion Battery [J].

Chou, Shu-Lei ;

Wang, Jia-Zhao ;

Liu, Hua-Kun ;

Dou, Shi-Xue .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (32) :16220-16227

[3] Insight into effects of graphene in Li4Ti5O12/carbon composite with high rate capability as anode materials for lithium ion batteries [J].

Ding, Y. ;

Li, G. R. ;

Xiao, C. W. ;

Gao, X. P. .

ELECTROCHIMICA ACTA, 2013, 102 :282-289

[4] THE SUPERCONDUCTOR-SEMICONDUCTOR TRANSITION IN THE LI1+XTI2-XO4 SPINEL SYSTEM [J].

HARRISON, MR ;

EDWARDS, PP ;

GOODENOUGH, JB .

PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1985, 52 (03) :679-699

[5] Graphene/Si multilayer structure anodes for advanced half and full lithium-ion cells [J].

Ji, Liwen ;

Zheng, Honghe ;

Ismach, Ariel ;

Tan, Zhongkui ;

Xun, Shidi ;

Lin, Eric ;

Battaglia, Vincent ;

Srinivasan, Venkat ;

Zhang, Yuegang .

NANO ENERGY, 2012, 1 (01) :164-171

[6] Electrodes with high power and high capacity for rechargeable lithium batteries [J].

Kang, KS ;

Meng, YS ;

Bréger, J ;

Grey, CP ;

Ceder, G .

SCIENCE, 2006, 311 (5763) :977-980

[7] Li4Ti5O12/reduced graphite oxide nano-hybrid material for high rate lithium-ion batteries [J].

Kim, Hyun-Kyung ;

Bak, Seong-Min ;

Kim, Kwang-Bum .

ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (12) :1768-1771

[8] Spinel Li4Ti5O12 Nanotubed for Energy Storage Materials [J].

Lee, Soon Chang ;

Lee, Sang Man ;

Lee, Jae Won ;

Lee, Jin Bae ;

Lee, Sang Moon ;

Han, Sang Sup ;

Lee, Hee Cheon ;

Kim, Hae Jin .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (42) :18420-18423

[9] A simple reduction process to synthesize MoO2/C composites with cage-like structure for high-performance lithium-ion batteries [J].

Liu, Bing ;

Zhao, Xinyu ;

Tian, Yuan ;

Zhao, Di ;

Hu, Changwen ;

Cao, Minhua .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (22) :8831-8837

[10] Comparison of microwave assisted solvothermal and hydrothermal syntheses of LiFePO4/C nanocomposite cathodes for lithium ion batteries [J].

Murugan, A. Vadivel ;

Muraliganth, T. ;

Manthiram, A. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (37) :14665-14671

← 1 2 3 4 →