A tetranuclear copper (II) complex with pyrazole-3,5-dicarboxylate ligands: synthesis, characterization and electrochemical properties

被引：5

作者：

Demir, Selcuk ^{[1
]}

Cepni, Hamide Merve ^{[1
]}

Holynska, Malgorzata ^{[2
]}

Kavanoz, Muammer ^{[1
]}

机构：

[1] Recep Tayyip Erdogan Univ, Dept Chem, Fac Arts & Sci, TR-53100 Rize, Turkey

[2] Univ Marburg, Dept Chem, D-35043 Marburg, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2016年 / 71卷 / 04期

关键词：

copper; crystal structure; polynuclear; pyrazole-3,5-dicarboxylic acid; thermal analysis; MAGNETIC-PROPERTIES; 3,5-PYRAZOLEDICARBOXYLIC ACID; CRYSTAL-STRUCTURES; CU(II) COMPLEXES; CHEMISTRY;

D O I：

10.1515/znb-2015-0197

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A tetranuclear copper (II) complex with pyrazole3,5-dicarboxylate ligands (pdc(3-)), [Me2NH2](4) [Cu-4(pdc)(4)], was synthesized using solvothermal and metal oxidation routes and characterized by elemental analysis, infrared, thermogravimetry/differential thermal analysis, and room-temperature magnetic measurements. The structure of the complex was determined by single-crystal X-ray diffraction. It comprises dimethylammonium cations and complex anions containing four Cu2+ cations. The crystal structure is stabilized by N-H center dot center dot center dot O hydrogen bonds. In addition, the electrochemical behavior was studied.

引用

页码：305 / 310

页数：6

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