Highly Efficient Hydrogenation of Furfural to Furfuryl Alcohol Catalyzed by Pt Supported on Bi-Metallic MIL-100 (Fe, Mn/Co) MOFs Derivates Prepared by Hydrothermal Polyol Reduction Method

被引：11

作者：

Sun, Wang ^{[1
]}

Luo, Lin ^{[1
]}

Li, Jiang ^{[1
]}

Tian, Xiqiang ^{[1
]}

Yan, Dong ^{[1
]}

Zhu, Yujun ^{[1
]}

机构：

[1] Heilongjiang Univ, Sch Chem & Mat, Minist Educ, Key Lab Funct Inorgan Mat Chem, Harbin 150080, Peoples R China

来源：

CATALYSIS LETTERS | 2022年 / 152卷 / 02期

基金：

黑龙江省自然科学基金;

关键词：

Pt; Bimetallic organic framework; MIL-100(Fe); Selective hydrogenation; Furfural; Furfuryl alcohol; METAL-ORGANIC FRAMEWORKS; SELECTIVE HYDROGENATION; PD NANOPARTICLES; CO2; UPTAKE; CU-BTC; CONVERSION; BIOMASS; CARBON; CINNAMALDEHYDE; ADSORPTION;

D O I：

10.1007/s10562-021-03656-y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Pt/(Fe, Mn/Co)-BTC catalysts were fabricated by a facile ultrasonic impregnation assisted hydrothermal polyol reduction method using first MIL-100(Fe, Mn/Co) MOFs as supports and tested for selective hydrogenation of furfural (FAL) to furfuryl alcohol (FOL). Various characterizations including XRD, TG, FT-IR, N-2 physical adsorption, ICP-OES, SEM, TEM and XPS were applied for exploring structure changes and surface properties of the catalysts. Over 98% conversion of FAL and 99% selectivity to FOL were achieved over Pt/(Fe, Mn)-BTC and Pt/(Fe, Co)-BTC, moreover, Pt/(Fe, Co)-BTC showed higher turnover frequency (TOF) of 1,044 h(-1) and better cycle stability, which are better than other catalysts prepared by using H-2, NaBH4, and formaldehyde as reductants. Overall, the formation of highly dispersed small-sized Pt NPs (about 1.7 nm) with much higher content of surface Pt-0 on the catalysts is the key of excellent hydrogenation activity due to the strong interaction between Pt NPs and the bimetallic supports.

引用

页码：570 / 584

页数：15

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