4-Phosphorylated 1,2-Disubstituted Imidazoles

被引：9
|
作者：
Huryeva, A. N. [1 ]
Marchenko, A. P. [1 ]
Koidan, G. N. [1 ]
Yurchenko, A. A. [1 ]
Zarudnitskii, E. V. [1 ]
Pinchuk, A. M. [1 ]
Kostyuk, A. N. [1 ]
机构：
[1] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02094 Kiev 94, Ukraine
来源：
HETEROATOM CHEMISTRY | 2010年 / 21卷 / 03期
关键词：
ACYLATION;
D O I：
10.1002/hc.20584
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
4-Selenophosphoryl-1,2-disubstituted imidazoles have been obtained by thermal decomposition of methyl 5-(diamidoselenophosphoryl)-imidazolium chlorides. The position of selenophosphoryl group in the imidazole ring was proved by H-1, C-13 NMR spectroscopy, and X-ray analysis. Previously unknown diamido- and dichloro(imidazol-4-yl)-phosphonites were synthesized, and differences in their reactivity compared to analogous 5-phosphorylated imidazoles are shown. (C) 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:103-118, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20584
引用
收藏
页码：103 / 118
页数：16
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