In situ FT-IR study of an electron-beam induced reaction of C60 film

被引：0

作者：

Hara, T ^{[1
]}

Onoe, J ^{[1
]}

Tanaka, H ^{[1
]}

Takeuchi, K ^{[1
]}

机构：

[1] RIKEN, Wako, Saitama 3510198, Japan

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2000年 / 340卷

关键词：

C-60; electron-beam; coalescence reaction; kinetics; bucky peanuts;

D O I：

10.1080/10587250008025549

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structural modification induced by electron-beam (EB) in a C-60 film and its kinetics have been studied using in situ high-resolution FT-IR spectroscopy. Similar to studies on photoirradiated KxC60 film, it was found that a coalescence reaction between adjacent C-60 molecules takes place, In order to investigate the interaction between an incident electron and C-60 molecules, the time-dependence of the amounts of C-60 On the EB irradiation was examined. It was found that the reaction rate exhibits a linear dependence on the reactant concentration and nonlinear dependence on the incident current.

引用

页码：695 / 700

页数：6

共 19 条

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