Improving the electrochemical performance by sulfonation of polyaniline-graphene-silica composite for high performance supercapacitor

被引：21
作者：
Ravi, Bolagam [1 ]
Rajender, Boddula [1 ]
Palaniappan, Srinivasan [1 ,2 ]
机构：
[1] CSIR Indian Inst Chem Technol, Polymers & Funct Mat Div, Hyderabad 500007, Telangana, India
[2] CSIR Network Inst Solar Energy NISE, New Delhi, India
来源：
INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS AND POLYMERIC BIOMATERIALS | 2016年 / 65卷 / 16期
关键词：
Graphene; polyaniline; sulfonation; supercapacitor; ternary composite; ENERGY-STORAGE; ELECTRODES; NANOCOMPOSITES;
D O I：
10.1080/00914037.2016.1171221
中图分类号：
TB3 [工程材料学]; R318.08 [生物材料学];
学科分类号：
0805 ; 080501 ; 080502 ;
摘要：
In this work, to increase the specific capacitance and energy density of reduced graphene oxide-silica composite (RGO-SiO2), pseudocapacitive behaviour of polyaniline is introduced to RGO-SiO2(PANI-RGO-SiO2) and further improved by sulfonating the polyaniline system (SPANI-RGO-SiO2). Formation of SPANI-RGO-SiO2 is confirmed from IR and XRD analyses. SPANI-RGO-SiO2 shows nanorods morphology with less crystalline nature. The specific capacitance of RGO-SiO2 is increases from 24 to 780 F g(-1) with sulfonation of polyaniline in RGO-SiO2. Retention in the specific capacitance value of SPANI-RGO-SiO2 is 85% with that of its original value of 780 F g(-1) with coulombic efficiency (96-99%). [GRAPHICS] .
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收藏
页码：835 / 840
页数：6
相关论文
共 35 条
  • [1] Synthesis of highly crystalline polyaniline with the use of (Cyclohexylamino)-1-propanesulfonic acid for supercapacitor
    Bolagam, Ravi
    Boddula, Rajender
    Srinivasan, Palaniappan
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2015, 45 (01) : 51 - 56
  • [2] Nanostructured polystyrene/polyaniline/graphene hybrid materials for electrochemical supercapacitor and Na-ion battery applications
    Chen, Jiucun
    Liu, Yinqin
    Li, Wenjun
    Wu, Chao
    Xu, Liqun
    Yang, Huan
    [J]. JOURNAL OF MATERIALS SCIENCE, 2015, 50 (16) : 5466 - 5474
  • [3] Chen SM, 2014, INT J ELECTROCHEM SC, V9, P4072
  • [4] Electrochemical capacitors utilising transition metal oxides: an update of recent developments
    Deng, Wentao
    Ji, Xiaobo
    Chen, Qiyuan
    Banks, Craig E.
    [J]. RSC ADVANCES, 2011, 1 (07) : 1171 - 1178
  • [5] Hierarchically structured graphene-based supercapacitor electrodes
    Dong, Lei
    Chen, Zhongxin
    Yang, Dong
    Lu, Hongbin
    [J]. RSC ADVANCES, 2013, 3 (44): : 21183 - 21191
  • [6] Synthesis of a graphene/polyaniline/MCM-41 nanocomposite and its application as a supercapacitor
    Feng, Xiaomiao
    Yan, Zhenzhen
    Chen, Ningna
    Zhang, Yu
    Liu, Xingfen
    Ma, Yanwen
    Yang, Xiaoyan
    Hou, Wenhua
    [J]. NEW JOURNAL OF CHEMISTRY, 2013, 37 (07) : 2203 - 2209
  • [7] Firsich DW, 1999, US Patent, Patent No. [5, 993,996A, 5993996]
  • [8] Supercapacitors based on conducting polymers/nanotubes composites
    Frackowiak, E
    Khomenko, V
    Jurewicz, K
    Lota, K
    Béguin, F
    [J]. JOURNAL OF POWER SOURCES, 2006, 153 (02) : 413 - 418
  • [9] Self-cleaning silica coatings on glass by single step sol-gel route
    Ganbavle, Vinayak V.
    Bangi, Uzma K. H.
    Latthe, Sanjay S.
    Mahadik, Satish A.
    Rao, A. Venkateswara
    [J]. SURFACE & COATINGS TECHNOLOGY, 2011, 205 (23-24) : 5338 - 5344
  • [10] Carbon-Based Electrochemical Capacitors
    Ghosh, Arunabha
    Lee, Young Hee
    [J]. CHEMSUSCHEM, 2012, 5 (03) : 480 - 499
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